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N-(3-Chloro-4-methyl­phen­yl)succinamic acid

In the crystal structure of the title compound, C(11)H(12)ClNO(3), the asymmetric unit contains two independent mol­ecules. The N—H bond in the amide segment is anti to the meta-Cl atom in the benzene ring, in both molecules. The amide and carboxyl C=O bonds are also anti to each other and anti to t...

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Detalles Bibliográficos
Autores principales: Chaithanya, U., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297894/
https://www.ncbi.nlm.nih.gov/pubmed/22412697
http://dx.doi.org/10.1107/S1600536812007623
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author Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
author_facet Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
author_sort Chaithanya, U.
collection PubMed
description In the crystal structure of the title compound, C(11)H(12)ClNO(3), the asymmetric unit contains two independent mol­ecules. The N—H bond in the amide segment is anti to the meta-Cl atom in the benzene ring, in both molecules. The amide and carboxyl C=O bonds are also anti to each other and anti to the H atoms on the adjacent –CH(2) groups. Furthermore, the C=O and O—H bonds of the acid group are in syn positions with respect to each other. The dihedral angles between the benzene ring and the amide group are 40.6 (2) and 44.9 (3)° in the two independent molecules. In the crystal, mol­ecules are packed into sheets parallel to the (11-3) plane through O—H⋯O and N—H⋯O hydrogen bonds.
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spelling pubmed-32978942012-03-12 N-(3-Chloro-4-methyl­phen­yl)succinamic acid Chaithanya, U. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(11)H(12)ClNO(3), the asymmetric unit contains two independent mol­ecules. The N—H bond in the amide segment is anti to the meta-Cl atom in the benzene ring, in both molecules. The amide and carboxyl C=O bonds are also anti to each other and anti to the H atoms on the adjacent –CH(2) groups. Furthermore, the C=O and O—H bonds of the acid group are in syn positions with respect to each other. The dihedral angles between the benzene ring and the amide group are 40.6 (2) and 44.9 (3)° in the two independent molecules. In the crystal, mol­ecules are packed into sheets parallel to the (11-3) plane through O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297894/ /pubmed/22412697 http://dx.doi.org/10.1107/S1600536812007623 Text en © Chaithanya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
N-(3-Chloro-4-methyl­phen­yl)succinamic acid
title N-(3-Chloro-4-methyl­phen­yl)succinamic acid
title_full N-(3-Chloro-4-methyl­phen­yl)succinamic acid
title_fullStr N-(3-Chloro-4-methyl­phen­yl)succinamic acid
title_full_unstemmed N-(3-Chloro-4-methyl­phen­yl)succinamic acid
title_short N-(3-Chloro-4-methyl­phen­yl)succinamic acid
title_sort n-(3-chloro-4-methyl­phen­yl)succinamic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297894/
https://www.ncbi.nlm.nih.gov/pubmed/22412697
http://dx.doi.org/10.1107/S1600536812007623
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