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(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide
The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thioamide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The molecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297895/ https://www.ncbi.nlm.nih.gov/pubmed/22412698 http://dx.doi.org/10.1107/S1600536812007039 |
Sumario: | The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thioamide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The molecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are interconnected through N—H⋯S hydrogen bonds to generate polymeric chains. The structure also features C—H⋯π interactions. An intramolecular O—H⋯O bond is also present. |
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