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(2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide

The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thio­amide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The mol­ecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the...

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Detalles Bibliográficos
Autores principales: Jacob, Jinsa Mary, Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297895/
https://www.ncbi.nlm.nih.gov/pubmed/22412698
http://dx.doi.org/10.1107/S1600536812007039
Descripción
Sumario:The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thio­amide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The mol­ecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are inter­connected through N—H⋯S hydrogen bonds to generate polymeric chains. The structure also features C—H⋯π interactions. An intra­molecular O—H⋯O bond is also present.