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(2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide

The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thio­amide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The mol­ecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the...

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Detalles Bibliográficos
Autores principales: Jacob, Jinsa Mary, Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297895/
https://www.ncbi.nlm.nih.gov/pubmed/22412698
http://dx.doi.org/10.1107/S1600536812007039
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author Jacob, Jinsa Mary
Kurup, M. R. Prathapachandra
author_facet Jacob, Jinsa Mary
Kurup, M. R. Prathapachandra
author_sort Jacob, Jinsa Mary
collection PubMed
description The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thio­amide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The mol­ecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are inter­connected through N—H⋯S hydrogen bonds to generate polymeric chains. The structure also features C—H⋯π interactions. An intra­molecular O—H⋯O bond is also present.
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spelling pubmed-32978952012-03-12 (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide Jacob, Jinsa Mary Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thio­amide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The mol­ecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are inter­connected through N—H⋯S hydrogen bonds to generate polymeric chains. The structure also features C—H⋯π interactions. An intra­molecular O—H⋯O bond is also present. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297895/ /pubmed/22412698 http://dx.doi.org/10.1107/S1600536812007039 Text en © Jacob and Kurup 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jacob, Jinsa Mary
Kurup, M. R. Prathapachandra
(2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide
title (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide
title_full (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide
title_fullStr (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide
title_full_unstemmed (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide
title_short (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-cyclo­hexyl­hydrazine­carbothio­amide
title_sort (2e)-2-(5-bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-n-cyclo­hexyl­hydrazine­carbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297895/
https://www.ncbi.nlm.nih.gov/pubmed/22412698
http://dx.doi.org/10.1107/S1600536812007039
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