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(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide
The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thioamide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The molecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297895/ https://www.ncbi.nlm.nih.gov/pubmed/22412698 http://dx.doi.org/10.1107/S1600536812007039 |
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author | Jacob, Jinsa Mary Kurup, M. R. Prathapachandra |
author_facet | Jacob, Jinsa Mary Kurup, M. R. Prathapachandra |
author_sort | Jacob, Jinsa Mary |
collection | PubMed |
description | The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thioamide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The molecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are interconnected through N—H⋯S hydrogen bonds to generate polymeric chains. The structure also features C—H⋯π interactions. An intramolecular O—H⋯O bond is also present. |
format | Online Article Text |
id | pubmed-3297895 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32978952012-03-12 (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide Jacob, Jinsa Mary Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thioamide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The molecules are paired through N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are interconnected through N—H⋯S hydrogen bonds to generate polymeric chains. The structure also features C—H⋯π interactions. An intramolecular O—H⋯O bond is also present. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297895/ /pubmed/22412698 http://dx.doi.org/10.1107/S1600536812007039 Text en © Jacob and Kurup 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jacob, Jinsa Mary Kurup, M. R. Prathapachandra (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
title | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
title_full | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
title_fullStr | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
title_full_unstemmed | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
title_short | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
title_sort | (2e)-2-(5-bromo-2-hydroxy-3-methoxybenzylidene)-n-cyclohexylhydrazinecarbothioamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297895/ https://www.ncbi.nlm.nih.gov/pubmed/22412698 http://dx.doi.org/10.1107/S1600536812007039 |
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