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2-(3-Amino­pyridinium-1-yl)-3-carb­oxy­propano­ate monohydrate

The title compound, C(9)H(10)N(2)O(4)·H(2)O, was obtained as a zwitterion derived from the nucleophilic attack of 3-amino­pyridine on the fumaric α,β-system. Within the molecule, the amino­pyridine moiety and the carboxyl­ate and carb­oxy­lic acid fragments form dihedral angles of 68.6 (2) and 62.8 ...

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Detalles Bibliográficos
Autores principales: Millán Corrales, Guadalupe, Morales-Morales, David, Hernández-Ortega, Simón, Campos-Gaxiola, José J., Cruz Enríquez, Adriana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297908/
https://www.ncbi.nlm.nih.gov/pubmed/22412711
http://dx.doi.org/10.1107/S1600536812006897
Descripción
Sumario:The title compound, C(9)H(10)N(2)O(4)·H(2)O, was obtained as a zwitterion derived from the nucleophilic attack of 3-amino­pyridine on the fumaric α,β-system. Within the molecule, the amino­pyridine moiety and the carboxyl­ate and carb­oxy­lic acid fragments form dihedral angles of 68.6 (2) and 62.8 (2)°, respectively. The geometry adopted by the mol­ecule does not allow the formation of centrosymmetric dimeric hydrogen-bonded units; instead chains along the a axis are linked by COO—H⋯OOC motifs. These chains are inter­connected by N—H⋯O and O—H⋯O hydrogen bonds involving the carb­oxy­lic acid and carboxyl­ate units and the solvent water mol­ecules.