2,2′-Dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate

The title compound, C(21)H(22)Br(2)N(4)·0.5H(2)O, contains two benzimidazole groups which may provide two potential coordination nodes for the construction of metal–organic frameworks. The mean planes of the two imidazole groups are almost perpendicular, with a dihedral angle of 83.05 (2)°, and adja...

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Detalles Bibliográficos
Autores principales: Wang, Xing, Liu, Chun-Bo, Wang, Shen-Tang, Yan, Yong-Sheng, Liu, Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297910/
https://www.ncbi.nlm.nih.gov/pubmed/22412713
http://dx.doi.org/10.1107/S1600536812007751
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author Wang, Xing
Liu, Chun-Bo
Wang, Shen-Tang
Yan, Yong-Sheng
Liu, Ling
author_facet Wang, Xing
Liu, Chun-Bo
Wang, Shen-Tang
Yan, Yong-Sheng
Liu, Ling
author_sort Wang, Xing
collection PubMed
description The title compound, C(21)H(22)Br(2)N(4)·0.5H(2)O, contains two benzimidazole groups which may provide two potential coordination nodes for the construction of metal–organic frameworks. The mean planes of the two imidazole groups are almost perpendicular, with a dihedral angle of 83.05 (2)°, and adjacent mol­ecules are linked into a one-dimensional chain by π–π stacking inter­actions between imidazole groups of different mol­ecules [centroid-to-centroid distances of 3.834 (2) and 3.522 (2) Å].
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spelling pubmed-32979102012-03-12 2,2′-Dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate Wang, Xing Liu, Chun-Bo Wang, Shen-Tang Yan, Yong-Sheng Liu, Ling Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(22)Br(2)N(4)·0.5H(2)O, contains two benzimidazole groups which may provide two potential coordination nodes for the construction of metal–organic frameworks. The mean planes of the two imidazole groups are almost perpendicular, with a dihedral angle of 83.05 (2)°, and adjacent mol­ecules are linked into a one-dimensional chain by π–π stacking inter­actions between imidazole groups of different mol­ecules [centroid-to-centroid distances of 3.834 (2) and 3.522 (2) Å]. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297910/ /pubmed/22412713 http://dx.doi.org/10.1107/S1600536812007751 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Xing
Liu, Chun-Bo
Wang, Shen-Tang
Yan, Yong-Sheng
Liu, Ling
2,2′-Dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate
title 2,2′-Dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate
title_full 2,2′-Dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate
title_fullStr 2,2′-Dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate
title_full_unstemmed 2,2′-Dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate
title_short 2,2′-Dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate
title_sort 2,2′-dimethyl-1,1′-[2,2-bis­(bromo­methyl)propane-1,3-di­yl]dibenzimidazole hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297910/
https://www.ncbi.nlm.nih.gov/pubmed/22412713
http://dx.doi.org/10.1107/S1600536812007751
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