N (2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N (2),N (7),N (7)-triphenyl-9H-fluorene-2,7-diamine

In the title mol­ecule, C(51)H(46)BrN(3), the central fluorene residue is planar (r.m.s. deviation = 0.0203 Å), as is the carbazole system (r.m.s. deviation = 0.0154 Å), and these groups are almost orthogonal [dihedral angle = 79.72 (3)°]. The three-dimensional architecture is consolidated by C—H⋯π...

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Detalles Bibliográficos
Autores principales: Baheti, Abhishek, Thomas, K. R. Justin, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297913/
https://www.ncbi.nlm.nih.gov/pubmed/22412716
http://dx.doi.org/10.1107/S160053681200791X
Descripción
Sumario:In the title mol­ecule, C(51)H(46)BrN(3), the central fluorene residue is planar (r.m.s. deviation = 0.0203 Å), as is the carbazole system (r.m.s. deviation = 0.0154 Å), and these groups are almost orthogonal [dihedral angle = 79.72 (3)°]. The three-dimensional architecture is consolidated by C—H⋯π inter­actions. The butyl substituent is disordered with two sites resolved for the terminal propyl atoms; the major component had a site-occupancy factor of 0.686 (3).

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