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N (2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N (2),N (7),N (7)-triphenyl-9H-fluorene-2,7-diamine
In the title molecule, C(51)H(46)BrN(3), the central fluorene residue is planar (r.m.s. deviation = 0.0203 Å), as is the carbazole system (r.m.s. deviation = 0.0154 Å), and these groups are almost orthogonal [dihedral angle = 79.72 (3)°]. The three-dimensional architecture is consolidated by C—H⋯π...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297913/ https://www.ncbi.nlm.nih.gov/pubmed/22412716 http://dx.doi.org/10.1107/S160053681200791X |
| _version_ | 1782225935964045312 |
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| author | Baheti, Abhishek Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Baheti, Abhishek Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Baheti, Abhishek |
| collection | PubMed |
| description | In the title molecule, C(51)H(46)BrN(3), the central fluorene residue is planar (r.m.s. deviation = 0.0203 Å), as is the carbazole system (r.m.s. deviation = 0.0154 Å), and these groups are almost orthogonal [dihedral angle = 79.72 (3)°]. The three-dimensional architecture is consolidated by C—H⋯π interactions. The butyl substituent is disordered with two sites resolved for the terminal propyl atoms; the major component had a site-occupancy factor of 0.686 (3). |
| format | Online Article Text |
| id | pubmed-3297913 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32979132012-03-12 N (2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N (2),N (7),N (7)-triphenyl-9H-fluorene-2,7-diamine Baheti, Abhishek Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(51)H(46)BrN(3), the central fluorene residue is planar (r.m.s. deviation = 0.0203 Å), as is the carbazole system (r.m.s. deviation = 0.0154 Å), and these groups are almost orthogonal [dihedral angle = 79.72 (3)°]. The three-dimensional architecture is consolidated by C—H⋯π interactions. The butyl substituent is disordered with two sites resolved for the terminal propyl atoms; the major component had a site-occupancy factor of 0.686 (3). International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297913/ /pubmed/22412716 http://dx.doi.org/10.1107/S160053681200791X Text en © Baheti et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Baheti, Abhishek Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. N (2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N (2),N (7),N (7)-triphenyl-9H-fluorene-2,7-diamine |
| title |
N
(2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N
(2),N
(7),N
(7)-triphenyl-9H-fluorene-2,7-diamine |
| title_full |
N
(2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N
(2),N
(7),N
(7)-triphenyl-9H-fluorene-2,7-diamine |
| title_fullStr |
N
(2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N
(2),N
(7),N
(7)-triphenyl-9H-fluorene-2,7-diamine |
| title_full_unstemmed |
N
(2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N
(2),N
(7),N
(7)-triphenyl-9H-fluorene-2,7-diamine |
| title_short |
N
(2)-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N
(2),N
(7),N
(7)-triphenyl-9H-fluorene-2,7-diamine |
| title_sort | n
(2)-(7-bromo-9-butyl-9h-carbazol-2-yl)-9,9-diethyl-n
(2),n
(7),n
(7)-triphenyl-9h-fluorene-2,7-diamine |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297913/ https://www.ncbi.nlm.nih.gov/pubmed/22412716 http://dx.doi.org/10.1107/S160053681200791X |
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