6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one

The title compound, C(15)H(12)N(2)OS, exists as the thione tautomer in the solid state. The phenyl group is almost perpendicular [dihedral angle = 87.96 (5)°] to the fused ring system (r.m.s. deviation = 0.036 Å for 13 ring and exocyclic non-H atoms). In the crystal, centrosymmetric dimers, sustaine...

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Autores principales: El-Azab, Adel S., Abdel-Aziz, Alaa A.-M., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297914/
https://www.ncbi.nlm.nih.gov/pubmed/22412717
http://dx.doi.org/10.1107/S1600536812007301
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author El-Azab, Adel S.
Abdel-Aziz, Alaa A.-M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet El-Azab, Adel S.
Abdel-Aziz, Alaa A.-M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort El-Azab, Adel S.
collection PubMed
description The title compound, C(15)H(12)N(2)OS, exists as the thione tautomer in the solid state. The phenyl group is almost perpendicular [dihedral angle = 87.96 (5)°] to the fused ring system (r.m.s. deviation = 0.036 Å for 13 ring and exocyclic non-H atoms). In the crystal, centrosymmetric dimers, sustained by pairs of N—H⋯S hydrogen bonds, are connected into layers parallel to (-101) by C—H⋯O and C—H⋯S inter­actions.
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spelling pubmed-32979142012-03-12 6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one El-Azab, Adel S. Abdel-Aziz, Alaa A.-M. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)N(2)OS, exists as the thione tautomer in the solid state. The phenyl group is almost perpendicular [dihedral angle = 87.96 (5)°] to the fused ring system (r.m.s. deviation = 0.036 Å for 13 ring and exocyclic non-H atoms). In the crystal, centrosymmetric dimers, sustained by pairs of N—H⋯S hydrogen bonds, are connected into layers parallel to (-101) by C—H⋯O and C—H⋯S inter­actions. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297914/ /pubmed/22412717 http://dx.doi.org/10.1107/S1600536812007301 Text en © El-Azab et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
El-Azab, Adel S.
Abdel-Aziz, Alaa A.-M.
Ng, Seik Weng
Tiekink, Edward R. T.
6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one
title 6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one
title_full 6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one
title_fullStr 6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one
title_full_unstemmed 6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one
title_short 6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one
title_sort 6-methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­quinazolin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297914/
https://www.ncbi.nlm.nih.gov/pubmed/22412717
http://dx.doi.org/10.1107/S1600536812007301
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