(1R*,2S*)-2-Nitro-1-(4-nitro­phen­yl)propanol

The title compound, C(9)H(10)N(2)O(5), presents a racemic mixture of two enanti­omeric diastereomers. In the crystal, mol­ecules assemble into zigzag chains parallel to the b axis [C(6) motif] due to the formation of elongated O—H⋯O(N) hydrogen bonds. Of inter­est is the fact that only the aliphatic...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Xu, Yang, Le, Zhang, Jun-na, He, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297929/
https://www.ncbi.nlm.nih.gov/pubmed/22412732
http://dx.doi.org/10.1107/S1600536812007775
_version_ 1782225939647692800
author Zhang, Xu
Yang, Le
Zhang, Jun-na
He, Wei
author_facet Zhang, Xu
Yang, Le
Zhang, Jun-na
He, Wei
author_sort Zhang, Xu
collection PubMed
description The title compound, C(9)H(10)N(2)O(5), presents a racemic mixture of two enanti­omeric diastereomers. In the crystal, mol­ecules assemble into zigzag chains parallel to the b axis [C(6) motif] due to the formation of elongated O—H⋯O(N) hydrogen bonds. Of inter­est is the fact that only the aliphatic nitro group is involved in hydrogen bonding and it adopts a gauche conformation with respect to the OH group.
format Online
Article
Text
id pubmed-3297929
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32979292012-03-12 (1R*,2S*)-2-Nitro-1-(4-nitro­phen­yl)propanol Zhang, Xu Yang, Le Zhang, Jun-na He, Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(10)N(2)O(5), presents a racemic mixture of two enanti­omeric diastereomers. In the crystal, mol­ecules assemble into zigzag chains parallel to the b axis [C(6) motif] due to the formation of elongated O—H⋯O(N) hydrogen bonds. Of inter­est is the fact that only the aliphatic nitro group is involved in hydrogen bonding and it adopts a gauche conformation with respect to the OH group. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297929/ /pubmed/22412732 http://dx.doi.org/10.1107/S1600536812007775 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Xu
Yang, Le
Zhang, Jun-na
He, Wei
(1R*,2S*)-2-Nitro-1-(4-nitro­phen­yl)propanol
title (1R*,2S*)-2-Nitro-1-(4-nitro­phen­yl)propanol
title_full (1R*,2S*)-2-Nitro-1-(4-nitro­phen­yl)propanol
title_fullStr (1R*,2S*)-2-Nitro-1-(4-nitro­phen­yl)propanol
title_full_unstemmed (1R*,2S*)-2-Nitro-1-(4-nitro­phen­yl)propanol
title_short (1R*,2S*)-2-Nitro-1-(4-nitro­phen­yl)propanol
title_sort (1r*,2s*)-2-nitro-1-(4-nitro­phen­yl)propanol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297929/
https://www.ncbi.nlm.nih.gov/pubmed/22412732
http://dx.doi.org/10.1107/S1600536812007775
work_keys_str_mv AT zhangxu 1r2s2nitro14nitrophenylpropanol
AT yangle 1r2s2nitro14nitrophenylpropanol
AT zhangjunna 1r2s2nitro14nitrophenylpropanol
AT hewei 1r2s2nitro14nitrophenylpropanol

Ejemplares similares