Cargando…
(E)-4-[(4-Diethylamino-2-hydroxybenzylidene)amino]benzonitrile
The title compound, C(18)H(19)N(3)O, displays an E conformation with respect to the C=N double bond. The dihedral angle between the mean planes of the two benzene rings is 24.49 (3)°. An intramolecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by nonclassical...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297948/ https://www.ncbi.nlm.nih.gov/pubmed/22412751 http://dx.doi.org/10.1107/S1600536812008082 |
_version_ | 1782225944008720384 |
---|---|
author | Chang, Ming-Jen Fang, Tzu-Chien Tsai, Hsing-Yang Luo, Ming-Hui Chen, Kew-Yu |
author_facet | Chang, Ming-Jen Fang, Tzu-Chien Tsai, Hsing-Yang Luo, Ming-Hui Chen, Kew-Yu |
author_sort | Chang, Ming-Jen |
collection | PubMed |
description | The title compound, C(18)H(19)N(3)O, displays an E conformation with respect to the C=N double bond. The dihedral angle between the mean planes of the two benzene rings is 24.49 (3)°. An intramolecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by nonclassical intermolecular C—H⋯O hydrogen bonds to form an infinite one-dimensional chain along [010], generating a C(8) motif. |
format | Online Article Text |
id | pubmed-3297948 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32979482012-03-12 (E)-4-[(4-Diethylamino-2-hydroxybenzylidene)amino]benzonitrile Chang, Ming-Jen Fang, Tzu-Chien Tsai, Hsing-Yang Luo, Ming-Hui Chen, Kew-Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(19)N(3)O, displays an E conformation with respect to the C=N double bond. The dihedral angle between the mean planes of the two benzene rings is 24.49 (3)°. An intramolecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by nonclassical intermolecular C—H⋯O hydrogen bonds to form an infinite one-dimensional chain along [010], generating a C(8) motif. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297948/ /pubmed/22412751 http://dx.doi.org/10.1107/S1600536812008082 Text en © Chang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chang, Ming-Jen Fang, Tzu-Chien Tsai, Hsing-Yang Luo, Ming-Hui Chen, Kew-Yu (E)-4-[(4-Diethylamino-2-hydroxybenzylidene)amino]benzonitrile |
title | (E)-4-[(4-Diethylamino-2-hydroxybenzylidene)amino]benzonitrile |
title_full | (E)-4-[(4-Diethylamino-2-hydroxybenzylidene)amino]benzonitrile |
title_fullStr | (E)-4-[(4-Diethylamino-2-hydroxybenzylidene)amino]benzonitrile |
title_full_unstemmed | (E)-4-[(4-Diethylamino-2-hydroxybenzylidene)amino]benzonitrile |
title_short | (E)-4-[(4-Diethylamino-2-hydroxybenzylidene)amino]benzonitrile |
title_sort | (e)-4-[(4-diethylamino-2-hydroxybenzylidene)amino]benzonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297948/ https://www.ncbi.nlm.nih.gov/pubmed/22412751 http://dx.doi.org/10.1107/S1600536812008082 |
work_keys_str_mv | AT changmingjen e44diethylamino2hydroxybenzylideneaminobenzonitrile AT fangtzuchien e44diethylamino2hydroxybenzylideneaminobenzonitrile AT tsaihsingyang e44diethylamino2hydroxybenzylideneaminobenzonitrile AT luominghui e44diethylamino2hydroxybenzylideneaminobenzonitrile AT chenkewyu e44diethylamino2hydroxybenzylideneaminobenzonitrile |