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N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine
In the title compound, C(30)H(34)N(4)S, each of the benzothiadiazole and fluorene fused ring systems is almost planar (r.m.s. deviations = 0.010 and 0.013 Å, respectively) and they are inclined to each other with a dihedral angle of 61.69 (3)°; the S atom is directed away from the rest of the mole...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297953/ https://www.ncbi.nlm.nih.gov/pubmed/22412756 http://dx.doi.org/10.1107/S1600536812008239 |
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author | Bolisetty, M. N. K. Prasad Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Bolisetty, M. N. K. Prasad Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Bolisetty, M. N. K. Prasad |
collection | PubMed |
description | In the title compound, C(30)H(34)N(4)S, each of the benzothiadiazole and fluorene fused ring systems is almost planar (r.m.s. deviations = 0.010 and 0.013 Å, respectively) and they are inclined to each other with a dihedral angle of 61.69 (3)°; the S atom is directed away from the rest of the molecule. Each of the benzothiadiazole ring N atoms forms a significant intramolecular contact, i.e. N—H⋯N or C—H⋯N. In the crystal, linear supramolecular chains along the c axis are generated by C—H⋯N interactions involving the tertiary amine N atom. |
format | Online Article Text |
id | pubmed-3297953 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32979532012-03-12 N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine Bolisetty, M. N. K. Prasad Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(34)N(4)S, each of the benzothiadiazole and fluorene fused ring systems is almost planar (r.m.s. deviations = 0.010 and 0.013 Å, respectively) and they are inclined to each other with a dihedral angle of 61.69 (3)°; the S atom is directed away from the rest of the molecule. Each of the benzothiadiazole ring N atoms forms a significant intramolecular contact, i.e. N—H⋯N or C—H⋯N. In the crystal, linear supramolecular chains along the c axis are generated by C—H⋯N interactions involving the tertiary amine N atom. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297953/ /pubmed/22412756 http://dx.doi.org/10.1107/S1600536812008239 Text en © Bolisetty et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bolisetty, M. N. K. Prasad Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine |
title |
N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine |
title_full |
N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine |
title_fullStr |
N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine |
title_full_unstemmed |
N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine |
title_short |
N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine |
title_sort | n-(9,9-dipropyl-9h-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297953/ https://www.ncbi.nlm.nih.gov/pubmed/22412756 http://dx.doi.org/10.1107/S1600536812008239 |
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