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N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine

In the title compound, C(30)H(34)N(4)S, each of the benzothia­diazole and fluorene fused ring systems is almost planar (r.m.s. deviations = 0.010 and 0.013 Å, respectively) and they are inclined to each other with a dihedral angle of 61.69 (3)°; the S atom is directed away from the rest of the mol­e...

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Detalles Bibliográficos
Autores principales: Bolisetty, M. N. K. Prasad, Thomas, K. R. Justin, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297953/
https://www.ncbi.nlm.nih.gov/pubmed/22412756
http://dx.doi.org/10.1107/S1600536812008239
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author Bolisetty, M. N. K. Prasad
Thomas, K. R. Justin
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Bolisetty, M. N. K. Prasad
Thomas, K. R. Justin
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Bolisetty, M. N. K. Prasad
collection PubMed
description In the title compound, C(30)H(34)N(4)S, each of the benzothia­diazole and fluorene fused ring systems is almost planar (r.m.s. deviations = 0.010 and 0.013 Å, respectively) and they are inclined to each other with a dihedral angle of 61.69 (3)°; the S atom is directed away from the rest of the mol­ecule. Each of the benzothiadiazole ring N atoms forms a significant intra­molecular contact, i.e. N—H⋯N or C—H⋯N. In the crystal, linear supra­molecular chains along the c axis are generated by C—H⋯N inter­actions involving the tertiary amine N atom.
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spelling pubmed-32979532012-03-12 N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine Bolisetty, M. N. K. Prasad Thomas, K. R. Justin Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(34)N(4)S, each of the benzothia­diazole and fluorene fused ring systems is almost planar (r.m.s. deviations = 0.010 and 0.013 Å, respectively) and they are inclined to each other with a dihedral angle of 61.69 (3)°; the S atom is directed away from the rest of the mol­ecule. Each of the benzothiadiazole ring N atoms forms a significant intra­molecular contact, i.e. N—H⋯N or C—H⋯N. In the crystal, linear supra­molecular chains along the c axis are generated by C—H⋯N inter­actions involving the tertiary amine N atom. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297953/ /pubmed/22412756 http://dx.doi.org/10.1107/S1600536812008239 Text en © Bolisetty et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bolisetty, M. N. K. Prasad
Thomas, K. R. Justin
Ng, Seik Weng
Tiekink, Edward R. T.
N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine
title N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine
title_full N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine
title_fullStr N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine
title_full_unstemmed N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine
title_short N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine
title_sort n-(9,9-dipropyl-9h-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothia­diazol-4-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297953/
https://www.ncbi.nlm.nih.gov/pubmed/22412756
http://dx.doi.org/10.1107/S1600536812008239
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