Ethyl N-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate

In the title compound, C(17)H(16)ClNO(2), the N=C—O—C—C fragment is planar within 0.029 (1) Å, and makes dihedral angles of 66.71 (8) and 59.61 (8)° with the planes of the chloro­phenyl and benzoyl rings, respectively. The carbonyl C=O bond is not coplanar with either of the aromatic rings; it makes...

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Autores principales: Sumathi, H. P., Dayananda, A. S., Dutkiewicz, Grzegorz, Yathirajan, H. S., Kubicki, Maciej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297957/
https://www.ncbi.nlm.nih.gov/pubmed/22412760
http://dx.doi.org/10.1107/S1600536812007763
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author Sumathi, H. P.
Dayananda, A. S.
Dutkiewicz, Grzegorz
Yathirajan, H. S.
Kubicki, Maciej
author_facet Sumathi, H. P.
Dayananda, A. S.
Dutkiewicz, Grzegorz
Yathirajan, H. S.
Kubicki, Maciej
author_sort Sumathi, H. P.
collection PubMed
description In the title compound, C(17)H(16)ClNO(2), the N=C—O—C—C fragment is planar within 0.029 (1) Å, and makes dihedral angles of 66.71 (8) and 59.61 (8)° with the planes of the chloro­phenyl and benzoyl rings, respectively. The carbonyl C=O bond is not coplanar with either of the aromatic rings; it makes angles of 42.5 and 23.5° with the normals to the ring planes. In the crystal, very weak C—H⋯O, C—H⋯Cl, C—H⋯π and π–π [inter­planar distance = 3.53 (1) Å] inter­actions are observed.
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spelling pubmed-32979572012-03-12 Ethyl N-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate Sumathi, H. P. Dayananda, A. S. Dutkiewicz, Grzegorz Yathirajan, H. S. Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(16)ClNO(2), the N=C—O—C—C fragment is planar within 0.029 (1) Å, and makes dihedral angles of 66.71 (8) and 59.61 (8)° with the planes of the chloro­phenyl and benzoyl rings, respectively. The carbonyl C=O bond is not coplanar with either of the aromatic rings; it makes angles of 42.5 and 23.5° with the normals to the ring planes. In the crystal, very weak C—H⋯O, C—H⋯Cl, C—H⋯π and π–π [inter­planar distance = 3.53 (1) Å] inter­actions are observed. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297957/ /pubmed/22412760 http://dx.doi.org/10.1107/S1600536812007763 Text en © Dayananda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sumathi, H. P.
Dayananda, A. S.
Dutkiewicz, Grzegorz
Yathirajan, H. S.
Kubicki, Maciej
Ethyl N-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate
title Ethyl N-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate
title_full Ethyl N-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate
title_fullStr Ethyl N-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate
title_full_unstemmed Ethyl N-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate
title_short Ethyl N-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate
title_sort ethyl n-(2-benzoyl-4-chloro­phen­yl)­ethane­carboximidate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297957/
https://www.ncbi.nlm.nih.gov/pubmed/22412760
http://dx.doi.org/10.1107/S1600536812007763
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