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Bis(2,6-dichlorobenzyl)selane
The title molecule, C(14)H(10)Cl(4)Se, features a selenide bridge between two dichlorobenzyl units. The dihedral angle between the two benzene rings is 107.9 (16)°. In the crystal, weak π–π face-to-face aromatic interactions are observed [centroid–centroid distance between two adjacent (but cryst...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297961/ https://www.ncbi.nlm.nih.gov/pubmed/22412764 http://dx.doi.org/10.1107/S1600536812008318 |
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author | Zhou, Mei-Yun Li, Yi-Qun Zheng, Wen-Jie |
author_facet | Zhou, Mei-Yun Li, Yi-Qun Zheng, Wen-Jie |
author_sort | Zhou, Mei-Yun |
collection | PubMed |
description | The title molecule, C(14)H(10)Cl(4)Se, features a selenide bridge between two dichlorobenzyl units. The dihedral angle between the two benzene rings is 107.9 (16)°. In the crystal, weak π–π face-to-face aromatic interactions are observed [centroid–centroid distance between two adjacent (but crystallographically different) phenyl rings = 3.885 (5) Å], providing some packing stability. Short Cl⋯Cl contacts of 3.41 (2) Å are observed. |
format | Online Article Text |
id | pubmed-3297961 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32979612012-03-12 Bis(2,6-dichlorobenzyl)selane Zhou, Mei-Yun Li, Yi-Qun Zheng, Wen-Jie Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(14)H(10)Cl(4)Se, features a selenide bridge between two dichlorobenzyl units. The dihedral angle between the two benzene rings is 107.9 (16)°. In the crystal, weak π–π face-to-face aromatic interactions are observed [centroid–centroid distance between two adjacent (but crystallographically different) phenyl rings = 3.885 (5) Å], providing some packing stability. Short Cl⋯Cl contacts of 3.41 (2) Å are observed. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297961/ /pubmed/22412764 http://dx.doi.org/10.1107/S1600536812008318 Text en © Zhou et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhou, Mei-Yun Li, Yi-Qun Zheng, Wen-Jie Bis(2,6-dichlorobenzyl)selane |
title | Bis(2,6-dichlorobenzyl)selane |
title_full | Bis(2,6-dichlorobenzyl)selane |
title_fullStr | Bis(2,6-dichlorobenzyl)selane |
title_full_unstemmed | Bis(2,6-dichlorobenzyl)selane |
title_short | Bis(2,6-dichlorobenzyl)selane |
title_sort | bis(2,6-dichlorobenzyl)selane |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297961/ https://www.ncbi.nlm.nih.gov/pubmed/22412764 http://dx.doi.org/10.1107/S1600536812008318 |
work_keys_str_mv | AT zhoumeiyun bis26dichlorobenzylselane AT liyiqun bis26dichlorobenzylselane AT zhengwenjie bis26dichlorobenzylselane |