(3-{[2,6-Bis(1-methyl­eth­yl)phen­yl]imino-κN}-1-phenyl­but-1-en-1-olato-κO)­di­methyl­aluminium

The mol­ecular structure of the title compound, [Al(CH(3))(2)(C(22)H(26)NO)], displays a monomer with the Al(III) atom in a distorted tetra­hedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O—Al—N bite angle of the chelating ligand is 94.14 ...

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Detalles Bibliográficos
Autores principales: Hao, Haijun, Zhu, Baichun, Yi, Jianjun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343778/
https://www.ncbi.nlm.nih.gov/pubmed/22589752
http://dx.doi.org/10.1107/S1600536812005880
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author Hao, Haijun
Zhu, Baichun
Yi, Jianjun
author_facet Hao, Haijun
Zhu, Baichun
Yi, Jianjun
author_sort Hao, Haijun
collection PubMed
description The mol­ecular structure of the title compound, [Al(CH(3))(2)(C(22)H(26)NO)], displays a monomer with the Al(III) atom in a distorted tetra­hedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O—Al—N bite angle of the chelating ligand is 94.14 (9)°. The O—C—C—C—N backbone of the ligand is nearly coplanar (r.m.s. deviation = 0.029 Å) and the Al atom deviates significantly from the mean plane by 0.525 (3) Å. In the crystal, weak inter­molecular C—H⋯O inter­actions are observed.
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spelling pubmed-33437782012-05-15 (3-{[2,6-Bis(1-methyl­eth­yl)phen­yl]imino-κN}-1-phenyl­but-1-en-1-olato-κO)­di­methyl­aluminium Hao, Haijun Zhu, Baichun Yi, Jianjun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular structure of the title compound, [Al(CH(3))(2)(C(22)H(26)NO)], displays a monomer with the Al(III) atom in a distorted tetra­hedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O—Al—N bite angle of the chelating ligand is 94.14 (9)°. The O—C—C—C—N backbone of the ligand is nearly coplanar (r.m.s. deviation = 0.029 Å) and the Al atom deviates significantly from the mean plane by 0.525 (3) Å. In the crystal, weak inter­molecular C—H⋯O inter­actions are observed. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343778/ /pubmed/22589752 http://dx.doi.org/10.1107/S1600536812005880 Text en © Hao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Haijun
Zhu, Baichun
Yi, Jianjun
(3-{[2,6-Bis(1-methyl­eth­yl)phen­yl]imino-κN}-1-phenyl­but-1-en-1-olato-κO)­di­methyl­aluminium
title (3-{[2,6-Bis(1-methyl­eth­yl)phen­yl]imino-κN}-1-phenyl­but-1-en-1-olato-κO)­di­methyl­aluminium
title_full (3-{[2,6-Bis(1-methyl­eth­yl)phen­yl]imino-κN}-1-phenyl­but-1-en-1-olato-κO)­di­methyl­aluminium
title_fullStr (3-{[2,6-Bis(1-methyl­eth­yl)phen­yl]imino-κN}-1-phenyl­but-1-en-1-olato-κO)­di­methyl­aluminium
title_full_unstemmed (3-{[2,6-Bis(1-methyl­eth­yl)phen­yl]imino-κN}-1-phenyl­but-1-en-1-olato-κO)­di­methyl­aluminium
title_short (3-{[2,6-Bis(1-methyl­eth­yl)phen­yl]imino-κN}-1-phenyl­but-1-en-1-olato-κO)­di­methyl­aluminium
title_sort (3-{[2,6-bis(1-methyl­eth­yl)phen­yl]imino-κn}-1-phenyl­but-1-en-1-olato-κo)­di­methyl­aluminium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343778/
https://www.ncbi.nlm.nih.gov/pubmed/22589752
http://dx.doi.org/10.1107/S1600536812005880
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