1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate

The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl­imidazolium) cation and a hexa­fluorido­phosphate anion. The ferrocenyl rings are skewed by 6.7 (4)° from the ideal eclipsed conformation. The inter­planar angle between the p...

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Detalles Bibliográficos
Autores principales: Nyamori, Vincent O., Zulu, Siphesihle M., Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343779/
https://www.ncbi.nlm.nih.gov/pubmed/22589753
http://dx.doi.org/10.1107/S1600536812008719
Descripción
Sumario:The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl­imidazolium) cation and a hexa­fluorido­phosphate anion. The ferrocenyl rings are skewed by 6.7 (4)° from the ideal eclipsed conformation. The inter­planar angle between the plane of the substituted cyclo­penta­dienyl ring and that of the imidazole ring is 89.9 (4)°. The crystal packing is stabilized by C—H⋯F hydrogen bonds.

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