1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate

The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl­imidazolium) cation and a hexa­fluorido­phosphate anion. The ferrocenyl rings are skewed by 6.7 (4)° from the ideal eclipsed conformation. The inter­planar angle between the p...

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Detalles Bibliográficos
Autores principales: Nyamori, Vincent O., Zulu, Siphesihle M., Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343779/
https://www.ncbi.nlm.nih.gov/pubmed/22589753
http://dx.doi.org/10.1107/S1600536812008719
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author Nyamori, Vincent O.
Zulu, Siphesihle M.
Omondi, Bernard
author_facet Nyamori, Vincent O.
Zulu, Siphesihle M.
Omondi, Bernard
author_sort Nyamori, Vincent O.
collection PubMed
description The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl­imidazolium) cation and a hexa­fluorido­phosphate anion. The ferrocenyl rings are skewed by 6.7 (4)° from the ideal eclipsed conformation. The inter­planar angle between the plane of the substituted cyclo­penta­dienyl ring and that of the imidazole ring is 89.9 (4)°. The crystal packing is stabilized by C—H⋯F hydrogen bonds.
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spelling pubmed-33437792012-05-15 1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate Nyamori, Vincent O. Zulu, Siphesihle M. Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl­imidazolium) cation and a hexa­fluorido­phosphate anion. The ferrocenyl rings are skewed by 6.7 (4)° from the ideal eclipsed conformation. The inter­planar angle between the plane of the substituted cyclo­penta­dienyl ring and that of the imidazole ring is 89.9 (4)°. The crystal packing is stabilized by C—H⋯F hydrogen bonds. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343779/ /pubmed/22589753 http://dx.doi.org/10.1107/S1600536812008719 Text en © Nyamori et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nyamori, Vincent O.
Zulu, Siphesihle M.
Omondi, Bernard
1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate
title 1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate
title_full 1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate
title_fullStr 1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate
title_full_unstemmed 1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate
title_short 1-(Ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate
title_sort 1-(ferrocen-1-ylmeth­yl)-3-methyl­imidazol-3-ium hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343779/
https://www.ncbi.nlm.nih.gov/pubmed/22589753
http://dx.doi.org/10.1107/S1600536812008719
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AT omondibernard 1ferrocen1ylmethyl3methylimidazol3iumhexafluoridophosphate

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