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Di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(IV)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)

The Sn, Cl and water O atoms of the title compound, [Sn(2)(CH(3))(4)Cl(4)(H(2)O)(2)]·C(10)H(20)O(5), lie on a special position of 2 site symmetry. The Sn(IV) atom shows cis-C(2)SnCl(2)O trigonal–bipyramidal coordination [C—Sn—C = 157.0 (1)°]; however, two [Me(2)SnCl(2)(H(2)O)] units are linked by a...

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Detalles Bibliográficos
Autores principales: Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343780/
https://www.ncbi.nlm.nih.gov/pubmed/22589754
http://dx.doi.org/10.1107/S1600536812008781
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author Amini, Mostafa M.
Ng, Seik Weng
author_facet Amini, Mostafa M.
Ng, Seik Weng
author_sort Amini, Mostafa M.
collection PubMed
description The Sn, Cl and water O atoms of the title compound, [Sn(2)(CH(3))(4)Cl(4)(H(2)O)(2)]·C(10)H(20)O(5), lie on a special position of 2 site symmetry. The Sn(IV) atom shows cis-C(2)SnCl(2)O trigonal–bipyramidal coordination [C—Sn—C = 157.0 (1)°]; however, two [Me(2)SnCl(2)(H(2)O)] units are linked by a tin–chlorine bridge [Sn←Cl = 3.247 (1) Å] across a center of inversion, generating a dinuclear species, so that the geometry is better regarded as a mer-C(2)SnCl(3)O octa­hedron. The crown ether inter­acts through O—H⋯O hydrogen with the metal atom through the coordinated water mol­ecules in an outer-sphere manner, generating a hydrogen-bonded chain running along [101]. The 15-crown-5 mol­ecule is disordered over the 2/m site.
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spelling pubmed-33437802012-05-15 Di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(IV)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1) Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn, Cl and water O atoms of the title compound, [Sn(2)(CH(3))(4)Cl(4)(H(2)O)(2)]·C(10)H(20)O(5), lie on a special position of 2 site symmetry. The Sn(IV) atom shows cis-C(2)SnCl(2)O trigonal–bipyramidal coordination [C—Sn—C = 157.0 (1)°]; however, two [Me(2)SnCl(2)(H(2)O)] units are linked by a tin–chlorine bridge [Sn←Cl = 3.247 (1) Å] across a center of inversion, generating a dinuclear species, so that the geometry is better regarded as a mer-C(2)SnCl(3)O octa­hedron. The crown ether inter­acts through O—H⋯O hydrogen with the metal atom through the coordinated water mol­ecules in an outer-sphere manner, generating a hydrogen-bonded chain running along [101]. The 15-crown-5 mol­ecule is disordered over the 2/m site. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343780/ /pubmed/22589754 http://dx.doi.org/10.1107/S1600536812008781 Text en © Amini and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Amini, Mostafa M.
Ng, Seik Weng
Di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(IV)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title Di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(IV)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_full Di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(IV)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_fullStr Di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(IV)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_full_unstemmed Di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(IV)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_short Di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(IV)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_sort di-μ-chlorido-bis­[aqua­chloridodimethyl­tin(iv)]–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343780/
https://www.ncbi.nlm.nih.gov/pubmed/22589754
http://dx.doi.org/10.1107/S1600536812008781
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