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Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1)
The Sn, Cl and water O atoms of the title compound, [Sn(2)(CH(3))(4)Cl(4)(H(2)O)(2)]·C(10)H(20)O(5), lie on a special position of 2 site symmetry. The Sn(IV) atom shows cis-C(2)SnCl(2)O trigonal–bipyramidal coordination [C—Sn—C = 157.0 (1)°]; however, two [Me(2)SnCl(2)(H(2)O)] units are linked by a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343780/ https://www.ncbi.nlm.nih.gov/pubmed/22589754 http://dx.doi.org/10.1107/S1600536812008781 |
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author | Amini, Mostafa M. Ng, Seik Weng |
author_facet | Amini, Mostafa M. Ng, Seik Weng |
author_sort | Amini, Mostafa M. |
collection | PubMed |
description | The Sn, Cl and water O atoms of the title compound, [Sn(2)(CH(3))(4)Cl(4)(H(2)O)(2)]·C(10)H(20)O(5), lie on a special position of 2 site symmetry. The Sn(IV) atom shows cis-C(2)SnCl(2)O trigonal–bipyramidal coordination [C—Sn—C = 157.0 (1)°]; however, two [Me(2)SnCl(2)(H(2)O)] units are linked by a tin–chlorine bridge [Sn←Cl = 3.247 (1) Å] across a center of inversion, generating a dinuclear species, so that the geometry is better regarded as a mer-C(2)SnCl(3)O octahedron. The crown ether interacts through O—H⋯O hydrogen with the metal atom through the coordinated water molecules in an outer-sphere manner, generating a hydrogen-bonded chain running along [101]. The 15-crown-5 molecule is disordered over the 2/m site. |
format | Online Article Text |
id | pubmed-3343780 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33437802012-05-15 Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1) Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn, Cl and water O atoms of the title compound, [Sn(2)(CH(3))(4)Cl(4)(H(2)O)(2)]·C(10)H(20)O(5), lie on a special position of 2 site symmetry. The Sn(IV) atom shows cis-C(2)SnCl(2)O trigonal–bipyramidal coordination [C—Sn—C = 157.0 (1)°]; however, two [Me(2)SnCl(2)(H(2)O)] units are linked by a tin–chlorine bridge [Sn←Cl = 3.247 (1) Å] across a center of inversion, generating a dinuclear species, so that the geometry is better regarded as a mer-C(2)SnCl(3)O octahedron. The crown ether interacts through O—H⋯O hydrogen with the metal atom through the coordinated water molecules in an outer-sphere manner, generating a hydrogen-bonded chain running along [101]. The 15-crown-5 molecule is disordered over the 2/m site. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343780/ /pubmed/22589754 http://dx.doi.org/10.1107/S1600536812008781 Text en © Amini and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Amini, Mostafa M. Ng, Seik Weng Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1) |
title | Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1) |
title_full | Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1) |
title_fullStr | Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1) |
title_full_unstemmed | Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1) |
title_short | Di-μ-chlorido-bis[aquachloridodimethyltin(IV)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1) |
title_sort | di-μ-chlorido-bis[aquachloridodimethyltin(iv)]–1,4,7,10,13-pentaoxacyclopentadecane (1/1) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343780/ https://www.ncbi.nlm.nih.gov/pubmed/22589754 http://dx.doi.org/10.1107/S1600536812008781 |
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