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[N′-(3-Eth­oxy-2-oxidobenzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazidato](methanol)dioxidomolybdenum(VI)

In the title dioxidomolybdenum(VI) complex, [Mo(C(17)H(16)N(2)O(5))O(2)(CH(3)OH)], the Mo(VI) atom is coordinated by the phenolate O, imine N and enolic O atoms of the tridentate hydrazone ligand, one methanol O atom, and two oxide O atoms, forming a distorted octa­hedral coordination geometry. The...

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Detalles Bibliográficos
Autor principal: Wang, Shou-Xing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343783/
https://www.ncbi.nlm.nih.gov/pubmed/22589757
http://dx.doi.org/10.1107/S1600536812008549
Descripción
Sumario:In the title dioxidomolybdenum(VI) complex, [Mo(C(17)H(16)N(2)O(5))O(2)(CH(3)OH)], the Mo(VI) atom is coordinated by the phenolate O, imine N and enolic O atoms of the tridentate hydrazone ligand, one methanol O atom, and two oxide O atoms, forming a distorted octa­hedral coordination geometry. The oxide O atoms adopt a cis conformation: one is trans to the methanol O atom and the other is trans to the ligand N atom. The dihedral angle between the two benzene rings in the hydrazone ligand is 4.0 (3)°. In the crystal, mol­ecules are linked by O—H⋯N and O—H⋯O hydrogen bonds.