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Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate

2,5-Bis(pyridin-2-yl)-1,3,4-thia­diazole (denoted L) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF(3)O(3)S)(C(12)H(8)N(4)S)(2)(H(2)O)](CF(3)O(3)S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thia­diazole ligand...

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Detalles Bibliográficos
Autores principales: Bentiss, Fouad, Outirite, Moha, Lagrenée, Michel, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343784/
https://www.ncbi.nlm.nih.gov/pubmed/22589758
http://dx.doi.org/10.1107/S1600536812008732
Descripción
Sumario:2,5-Bis(pyridin-2-yl)-1,3,4-thia­diazole (denoted L) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF(3)O(3)S)(C(12)H(8)N(4)S)(2)(H(2)O)](CF(3)O(3)S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thia­diazole ligands, one water mol­ecule and one trifluoro­methane­sulfonate anion. The second trifluoro­methane­sulfonate anion does not coordinate the copper(II) cation. Each thia­diazole ligand uses one pyridyl and one thia­diazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thia­diazole ring as the S atom. The trifluoro­methane­sulfonate ions are involved in a three-dimensional network of O—H⋯O hydrogen bonds. C—H⋯N inter­actions also occur.