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Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate

2,5-Bis(pyridin-2-yl)-1,3,4-thia­diazole (denoted L) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF(3)O(3)S)(C(12)H(8)N(4)S)(2)(H(2)O)](CF(3)O(3)S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thia­diazole ligand...

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Autores principales: Bentiss, Fouad, Outirite, Moha, Lagrenée, Michel, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343784/
https://www.ncbi.nlm.nih.gov/pubmed/22589758
http://dx.doi.org/10.1107/S1600536812008732
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author Bentiss, Fouad
Outirite, Moha
Lagrenée, Michel
Saadi, Mohamed
El Ammari, Lahcen
author_facet Bentiss, Fouad
Outirite, Moha
Lagrenée, Michel
Saadi, Mohamed
El Ammari, Lahcen
author_sort Bentiss, Fouad
collection PubMed
description 2,5-Bis(pyridin-2-yl)-1,3,4-thia­diazole (denoted L) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF(3)O(3)S)(C(12)H(8)N(4)S)(2)(H(2)O)](CF(3)O(3)S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thia­diazole ligands, one water mol­ecule and one trifluoro­methane­sulfonate anion. The second trifluoro­methane­sulfonate anion does not coordinate the copper(II) cation. Each thia­diazole ligand uses one pyridyl and one thia­diazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thia­diazole ring as the S atom. The trifluoro­methane­sulfonate ions are involved in a three-dimensional network of O—H⋯O hydrogen bonds. C—H⋯N inter­actions also occur.
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spelling pubmed-33437842012-05-15 Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate Bentiss, Fouad Outirite, Moha Lagrenée, Michel Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers 2,5-Bis(pyridin-2-yl)-1,3,4-thia­diazole (denoted L) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF(3)O(3)S)(C(12)H(8)N(4)S)(2)(H(2)O)](CF(3)O(3)S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thia­diazole ligands, one water mol­ecule and one trifluoro­methane­sulfonate anion. The second trifluoro­methane­sulfonate anion does not coordinate the copper(II) cation. Each thia­diazole ligand uses one pyridyl and one thia­diazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thia­diazole ring as the S atom. The trifluoro­methane­sulfonate ions are involved in a three-dimensional network of O—H⋯O hydrogen bonds. C—H⋯N inter­actions also occur. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343784/ /pubmed/22589758 http://dx.doi.org/10.1107/S1600536812008732 Text en © Bentiss et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bentiss, Fouad
Outirite, Moha
Lagrenée, Michel
Saadi, Mohamed
El Ammari, Lahcen
Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate
title Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate
title_full Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate
title_fullStr Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate
title_full_unstemmed Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate
title_short Aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)](trifluoro­methane­sulfonato-κO)copper(II) trifluoro­methane­sulfonate
title_sort aqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) n (2),n (3)](trifluoro­methane­sulfonato-κo)copper(ii) trifluoro­methane­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343784/
https://www.ncbi.nlm.nih.gov/pubmed/22589758
http://dx.doi.org/10.1107/S1600536812008732
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