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Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2) N (2),N (3)](trifluoromethanesulfonato-κO)copper(II) trifluoromethanesulfonate
2,5-Bis(pyridin-2-yl)-1,3,4-thiadiazole (denoted L) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF(3)O(3)S)(C(12)H(8)N(4)S)(2)(H(2)O)](CF(3)O(3)S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thiadiazole ligand...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343784/ https://www.ncbi.nlm.nih.gov/pubmed/22589758 http://dx.doi.org/10.1107/S1600536812008732 |
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author | Bentiss, Fouad Outirite, Moha Lagrenée, Michel Saadi, Mohamed El Ammari, Lahcen |
author_facet | Bentiss, Fouad Outirite, Moha Lagrenée, Michel Saadi, Mohamed El Ammari, Lahcen |
author_sort | Bentiss, Fouad |
collection | PubMed |
description | 2,5-Bis(pyridin-2-yl)-1,3,4-thiadiazole (denoted L) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF(3)O(3)S)(C(12)H(8)N(4)S)(2)(H(2)O)](CF(3)O(3)S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thiadiazole ligands, one water molecule and one trifluoromethanesulfonate anion. The second trifluoromethanesulfonate anion does not coordinate the copper(II) cation. Each thiadiazole ligand uses one pyridyl and one thiadiazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thiadiazole ring as the S atom. The trifluoromethanesulfonate ions are involved in a three-dimensional network of O—H⋯O hydrogen bonds. C—H⋯N interactions also occur. |
format | Online Article Text |
id | pubmed-3343784 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33437842012-05-15 Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2) N (2),N (3)](trifluoromethanesulfonato-κO)copper(II) trifluoromethanesulfonate Bentiss, Fouad Outirite, Moha Lagrenée, Michel Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers 2,5-Bis(pyridin-2-yl)-1,3,4-thiadiazole (denoted L) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF(3)O(3)S)(C(12)H(8)N(4)S)(2)(H(2)O)](CF(3)O(3)S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thiadiazole ligands, one water molecule and one trifluoromethanesulfonate anion. The second trifluoromethanesulfonate anion does not coordinate the copper(II) cation. Each thiadiazole ligand uses one pyridyl and one thiadiazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thiadiazole ring as the S atom. The trifluoromethanesulfonate ions are involved in a three-dimensional network of O—H⋯O hydrogen bonds. C—H⋯N interactions also occur. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343784/ /pubmed/22589758 http://dx.doi.org/10.1107/S1600536812008732 Text en © Bentiss et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bentiss, Fouad Outirite, Moha Lagrenée, Michel Saadi, Mohamed El Ammari, Lahcen Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2) N (2),N (3)](trifluoromethanesulfonato-κO)copper(II) trifluoromethanesulfonate |
title | Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2)
N
(2),N
(3)](trifluoromethanesulfonato-κO)copper(II) trifluoromethanesulfonate |
title_full | Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2)
N
(2),N
(3)](trifluoromethanesulfonato-κO)copper(II) trifluoromethanesulfonate |
title_fullStr | Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2)
N
(2),N
(3)](trifluoromethanesulfonato-κO)copper(II) trifluoromethanesulfonate |
title_full_unstemmed | Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2)
N
(2),N
(3)](trifluoromethanesulfonato-κO)copper(II) trifluoromethanesulfonate |
title_short | Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2)
N
(2),N
(3)](trifluoromethanesulfonato-κO)copper(II) trifluoromethanesulfonate |
title_sort | aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2)
n
(2),n
(3)](trifluoromethanesulfonato-κo)copper(ii) trifluoromethanesulfonate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343784/ https://www.ncbi.nlm.nih.gov/pubmed/22589758 http://dx.doi.org/10.1107/S1600536812008732 |
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