Poly[octakis(1H-imidazole-κN (3))octa-μ-oxido-tetra­oxidodicopper(II)tetra­vanadate(V)]

In the title inorganic–organic hybrid compound, [Cu(2)V(4)O(12)(C(3)H(4)N(2))(8)](n), the V(V) ion is tetra­coordinated by four O atoms and the Cu(II) ion is hexa­coordinated by four N atoms from four imidazole ligands and two O atoms from two tetra­hedral vanadate (VO(4)) units in a distorted octa­...

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Autores principales: Chanthee, Songwuit, Saesong, Tongchai, Saphu, Watcharin, Chainok, Kittipong, Krachodnok, Samroeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343785/
https://www.ncbi.nlm.nih.gov/pubmed/22589759
http://dx.doi.org/10.1107/S1600536812008252
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author Chanthee, Songwuit
Saesong, Tongchai
Saphu, Watcharin
Chainok, Kittipong
Krachodnok, Samroeng
author_facet Chanthee, Songwuit
Saesong, Tongchai
Saphu, Watcharin
Chainok, Kittipong
Krachodnok, Samroeng
author_sort Chanthee, Songwuit
collection PubMed
description In the title inorganic–organic hybrid compound, [Cu(2)V(4)O(12)(C(3)H(4)N(2))(8)](n), the V(V) ion is tetra­coordinated by four O atoms and the Cu(II) ion is hexa­coordinated by four N atoms from four imidazole ligands and two O atoms from two tetra­hedral vanadate (VO(4)) units in a distorted octa­hedral geometry. The structure consists of two-dimensional sheets constructed from centrosymmetric cyclic [V(4)O(12)](4−) anions covalently bound through O to [Cu(imidazole)(4)](2+) cations. Adjacent sheets are linked by N—H⋯O hydrogen bonds and weak C—H⋯π inter­actions (H⋯centroid distances = 2.59, 2.66, 2.76, 2.91 and 2.98 Å into a three-dimensional supra­molecular network.
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spelling pubmed-33437852012-05-15 Poly[octakis(1H-imidazole-κN (3))octa-μ-oxido-tetra­oxidodicopper(II)tetra­vanadate(V)] Chanthee, Songwuit Saesong, Tongchai Saphu, Watcharin Chainok, Kittipong Krachodnok, Samroeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title inorganic–organic hybrid compound, [Cu(2)V(4)O(12)(C(3)H(4)N(2))(8)](n), the V(V) ion is tetra­coordinated by four O atoms and the Cu(II) ion is hexa­coordinated by four N atoms from four imidazole ligands and two O atoms from two tetra­hedral vanadate (VO(4)) units in a distorted octa­hedral geometry. The structure consists of two-dimensional sheets constructed from centrosymmetric cyclic [V(4)O(12)](4−) anions covalently bound through O to [Cu(imidazole)(4)](2+) cations. Adjacent sheets are linked by N—H⋯O hydrogen bonds and weak C—H⋯π inter­actions (H⋯centroid distances = 2.59, 2.66, 2.76, 2.91 and 2.98 Å into a three-dimensional supra­molecular network. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343785/ /pubmed/22589759 http://dx.doi.org/10.1107/S1600536812008252 Text en © Chanthee et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chanthee, Songwuit
Saesong, Tongchai
Saphu, Watcharin
Chainok, Kittipong
Krachodnok, Samroeng
Poly[octakis(1H-imidazole-κN (3))octa-μ-oxido-tetra­oxidodicopper(II)tetra­vanadate(V)]
title Poly[octakis(1H-imidazole-κN (3))octa-μ-oxido-tetra­oxidodicopper(II)tetra­vanadate(V)]
title_full Poly[octakis(1H-imidazole-κN (3))octa-μ-oxido-tetra­oxidodicopper(II)tetra­vanadate(V)]
title_fullStr Poly[octakis(1H-imidazole-κN (3))octa-μ-oxido-tetra­oxidodicopper(II)tetra­vanadate(V)]
title_full_unstemmed Poly[octakis(1H-imidazole-κN (3))octa-μ-oxido-tetra­oxidodicopper(II)tetra­vanadate(V)]
title_short Poly[octakis(1H-imidazole-κN (3))octa-μ-oxido-tetra­oxidodicopper(II)tetra­vanadate(V)]
title_sort poly[octakis(1h-imidazole-κn (3))octa-μ-oxido-tetra­oxidodicopper(ii)tetra­vanadate(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343785/
https://www.ncbi.nlm.nih.gov/pubmed/22589759
http://dx.doi.org/10.1107/S1600536812008252
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