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Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium]
The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis[4-(ethyl-carboxyl)-phenoxyl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms,...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343791/ https://www.ncbi.nlm.nih.gov/pubmed/22589765 http://dx.doi.org/10.1107/S1600536812008513 |
Sumario: | The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis[4-(ethyl-carboxyl)-phenoxyl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms, two from the chelating carboxylate group of the anion and four from four neighboring and monodentately binding anions, giving rise to an irregular [KO(6)] coordination polyhedron. The coordination mode of the cation leads to the formation of K/O layers parallel to (100). These layers are linked by the nearly coplanar anions (r.m.s. deviation of 0.064 Å of the carboxyl, aryl and O—CH(2) groups from the least-squares plane) into a three-dimentional network. |
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