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Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]

The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis­[4-(ethyl-carbox­yl)-phenox­yl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms,...

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Detalles Bibliográficos
Autores principales: Ma, Zhen, Liang, Baohuan, Lu, Wanbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343791/
https://www.ncbi.nlm.nih.gov/pubmed/22589765
http://dx.doi.org/10.1107/S1600536812008513
Descripción
Sumario:The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis­[4-(ethyl-carbox­yl)-phenox­yl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms, two from the chelating carboxyl­ate group of the anion and four from four neighboring and monodentately binding anions, giving rise to an irregular [KO(6)] coordination polyhedron. The coordination mode of the cation leads to the formation of K/O layers parallel to (100). These layers are linked by the nearly coplanar anions (r.m.s. deviation of 0.064 Å of the carboxyl, aryl and O—CH(2) groups from the least-squares plane) into a three-dimentional network.