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Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium]
The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis[4-(ethyl-carboxyl)-phenoxyl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms,...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343791/ https://www.ncbi.nlm.nih.gov/pubmed/22589765 http://dx.doi.org/10.1107/S1600536812008513 |
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author | Ma, Zhen Liang, Baohuan Lu, Wanbing |
author_facet | Ma, Zhen Liang, Baohuan Lu, Wanbing |
author_sort | Ma, Zhen |
collection | PubMed |
description | The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis[4-(ethyl-carboxyl)-phenoxyl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms, two from the chelating carboxylate group of the anion and four from four neighboring and monodentately binding anions, giving rise to an irregular [KO(6)] coordination polyhedron. The coordination mode of the cation leads to the formation of K/O layers parallel to (100). These layers are linked by the nearly coplanar anions (r.m.s. deviation of 0.064 Å of the carboxyl, aryl and O—CH(2) groups from the least-squares plane) into a three-dimentional network. |
format | Online Article Text |
id | pubmed-3343791 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33437912012-05-15 Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium] Ma, Zhen Liang, Baohuan Lu, Wanbing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis[4-(ethyl-carboxyl)-phenoxyl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms, two from the chelating carboxylate group of the anion and four from four neighboring and monodentately binding anions, giving rise to an irregular [KO(6)] coordination polyhedron. The coordination mode of the cation leads to the formation of K/O layers parallel to (100). These layers are linked by the nearly coplanar anions (r.m.s. deviation of 0.064 Å of the carboxyl, aryl and O—CH(2) groups from the least-squares plane) into a three-dimentional network. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343791/ /pubmed/22589765 http://dx.doi.org/10.1107/S1600536812008513 Text en © Ma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Zhen Liang, Baohuan Lu, Wanbing Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium] |
title | Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium] |
title_full | Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium] |
title_fullStr | Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium] |
title_full_unstemmed | Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium] |
title_short | Poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium] |
title_sort | poly[[μ(10)-4,4′-(ethane-1,2-diyldioxy)dibenzoato]dipotassium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343791/ https://www.ncbi.nlm.nih.gov/pubmed/22589765 http://dx.doi.org/10.1107/S1600536812008513 |
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