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Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]

The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis­[4-(ethyl-carbox­yl)-phenox­yl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms,...

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Detalles Bibliográficos
Autores principales: Ma, Zhen, Liang, Baohuan, Lu, Wanbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343791/
https://www.ncbi.nlm.nih.gov/pubmed/22589765
http://dx.doi.org/10.1107/S1600536812008513
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author Ma, Zhen
Liang, Baohuan
Lu, Wanbing
author_facet Ma, Zhen
Liang, Baohuan
Lu, Wanbing
author_sort Ma, Zhen
collection PubMed
description The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis­[4-(ethyl-carbox­yl)-phenox­yl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms, two from the chelating carboxyl­ate group of the anion and four from four neighboring and monodentately binding anions, giving rise to an irregular [KO(6)] coordination polyhedron. The coordination mode of the cation leads to the formation of K/O layers parallel to (100). These layers are linked by the nearly coplanar anions (r.m.s. deviation of 0.064 Å of the carboxyl, aryl and O—CH(2) groups from the least-squares plane) into a three-dimentional network.
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spelling pubmed-33437912012-05-15 Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium] Ma, Zhen Liang, Baohuan Lu, Wanbing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, [K(2)(C(16)H(12)O(6))](n), was obtained by the reaction of 1,2-bis­[4-(ethyl-carbox­yl)-phenox­yl]ethane with KOH in water. The anion lies on a crystallographic inversion center, which is located at the mid-point of the central C—C bond. The K(+) cation is coordinated by six O atoms, two from the chelating carboxyl­ate group of the anion and four from four neighboring and monodentately binding anions, giving rise to an irregular [KO(6)] coordination polyhedron. The coordination mode of the cation leads to the formation of K/O layers parallel to (100). These layers are linked by the nearly coplanar anions (r.m.s. deviation of 0.064 Å of the carboxyl, aryl and O—CH(2) groups from the least-squares plane) into a three-dimentional network. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343791/ /pubmed/22589765 http://dx.doi.org/10.1107/S1600536812008513 Text en © Ma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Zhen
Liang, Baohuan
Lu, Wanbing
Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]
title Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]
title_full Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]
title_fullStr Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]
title_full_unstemmed Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]
title_short Poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]
title_sort poly[[μ(10)-4,4′-(ethane-1,2-diyldi­oxy)dibenzoato]dipotassium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343791/
https://www.ncbi.nlm.nih.gov/pubmed/22589765
http://dx.doi.org/10.1107/S1600536812008513
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