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Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate

In the title complex, [Ni(2)(C(14)H(17)NO(4))(2)(C(12)H(8)N(2))(2)]·4CH(3)OH·3H(2)O, the two Ni(II) ions are bridged by two Schiff base anions, leading to a dinuclear complex. One Ni(II) ion is six-coordinated by four O atoms and two N atoms of two tridentate Schiff base ligands derived from the con...

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Detalles Bibliográficos
Autores principales: Li, Yan, Guo, Zhenghua, Dong, Jianfang, Li, Lianzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343792/
https://www.ncbi.nlm.nih.gov/pubmed/22589766
http://dx.doi.org/10.1107/S1600536812008987
Descripción
Sumario:In the title complex, [Ni(2)(C(14)H(17)NO(4))(2)(C(12)H(8)N(2))(2)]·4CH(3)OH·3H(2)O, the two Ni(II) ions are bridged by two Schiff base anions, leading to a dinuclear complex. One Ni(II) ion is six-coordinated by four O atoms and two N atoms of two tridentate Schiff base ligands derived from the condensation of l-isoleucine and o-vanillin. The other Ni(II) ion is six-coordinated by four N atoms of two 1,10-phenanthroline ligands and two O atoms of the Schiff base ligands. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds lead to a three-dimensional structure. Intra­molecular C—H⋯O hydrogen bonds are also present. One of the methyl groups of the l-isoleucinate moieties is disordered over two sets of sites with an occupancy ratio of 0.687 (19):0.313 (19) and two methanol mol­ecules are half-occupied.