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Bis[μ-N-(3-methoxy-2-oxidobenzylidene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetrasolvate trihydrate
In the title complex, [Ni(2)(C(14)H(17)NO(4))(2)(C(12)H(8)N(2))(2)]·4CH(3)OH·3H(2)O, the two Ni(II) ions are bridged by two Schiff base anions, leading to a dinuclear complex. One Ni(II) ion is six-coordinated by four O atoms and two N atoms of two tridentate Schiff base ligands derived from the con...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343792/ https://www.ncbi.nlm.nih.gov/pubmed/22589766 http://dx.doi.org/10.1107/S1600536812008987 |
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author | Li, Yan Guo, Zhenghua Dong, Jianfang Li, Lianzhi |
author_facet | Li, Yan Guo, Zhenghua Dong, Jianfang Li, Lianzhi |
author_sort | Li, Yan |
collection | PubMed |
description | In the title complex, [Ni(2)(C(14)H(17)NO(4))(2)(C(12)H(8)N(2))(2)]·4CH(3)OH·3H(2)O, the two Ni(II) ions are bridged by two Schiff base anions, leading to a dinuclear complex. One Ni(II) ion is six-coordinated by four O atoms and two N atoms of two tridentate Schiff base ligands derived from the condensation of l-isoleucine and o-vanillin. The other Ni(II) ion is six-coordinated by four N atoms of two 1,10-phenanthroline ligands and two O atoms of the Schiff base ligands. In the crystal, intermolecular O—H⋯O and C—H⋯O hydrogen bonds lead to a three-dimensional structure. Intramolecular C—H⋯O hydrogen bonds are also present. One of the methyl groups of the l-isoleucinate moieties is disordered over two sets of sites with an occupancy ratio of 0.687 (19):0.313 (19) and two methanol molecules are half-occupied. |
format | Online Article Text |
id | pubmed-3343792 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33437922012-05-15 Bis[μ-N-(3-methoxy-2-oxidobenzylidene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetrasolvate trihydrate Li, Yan Guo, Zhenghua Dong, Jianfang Li, Lianzhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(2)(C(14)H(17)NO(4))(2)(C(12)H(8)N(2))(2)]·4CH(3)OH·3H(2)O, the two Ni(II) ions are bridged by two Schiff base anions, leading to a dinuclear complex. One Ni(II) ion is six-coordinated by four O atoms and two N atoms of two tridentate Schiff base ligands derived from the condensation of l-isoleucine and o-vanillin. The other Ni(II) ion is six-coordinated by four N atoms of two 1,10-phenanthroline ligands and two O atoms of the Schiff base ligands. In the crystal, intermolecular O—H⋯O and C—H⋯O hydrogen bonds lead to a three-dimensional structure. Intramolecular C—H⋯O hydrogen bonds are also present. One of the methyl groups of the l-isoleucinate moieties is disordered over two sets of sites with an occupancy ratio of 0.687 (19):0.313 (19) and two methanol molecules are half-occupied. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343792/ /pubmed/22589766 http://dx.doi.org/10.1107/S1600536812008987 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Yan Guo, Zhenghua Dong, Jianfang Li, Lianzhi Bis[μ-N-(3-methoxy-2-oxidobenzylidene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetrasolvate trihydrate |
title | Bis[μ-N-(3-methoxy-2-oxidobenzylidene-1:2κ(2)
O
(2):O
(2))-l-isoleucinato-2κ(2)
N,O]bis(1,10-phenanthroline-1κ(2)
N,N′)dinickel(II) methanol tetrasolvate trihydrate |
title_full | Bis[μ-N-(3-methoxy-2-oxidobenzylidene-1:2κ(2)
O
(2):O
(2))-l-isoleucinato-2κ(2)
N,O]bis(1,10-phenanthroline-1κ(2)
N,N′)dinickel(II) methanol tetrasolvate trihydrate |
title_fullStr | Bis[μ-N-(3-methoxy-2-oxidobenzylidene-1:2κ(2)
O
(2):O
(2))-l-isoleucinato-2κ(2)
N,O]bis(1,10-phenanthroline-1κ(2)
N,N′)dinickel(II) methanol tetrasolvate trihydrate |
title_full_unstemmed | Bis[μ-N-(3-methoxy-2-oxidobenzylidene-1:2κ(2)
O
(2):O
(2))-l-isoleucinato-2κ(2)
N,O]bis(1,10-phenanthroline-1κ(2)
N,N′)dinickel(II) methanol tetrasolvate trihydrate |
title_short | Bis[μ-N-(3-methoxy-2-oxidobenzylidene-1:2κ(2)
O
(2):O
(2))-l-isoleucinato-2κ(2)
N,O]bis(1,10-phenanthroline-1κ(2)
N,N′)dinickel(II) methanol tetrasolvate trihydrate |
title_sort | bis[μ-n-(3-methoxy-2-oxidobenzylidene-1:2κ(2)
o
(2):o
(2))-l-isoleucinato-2κ(2)
n,o]bis(1,10-phenanthroline-1κ(2)
n,n′)dinickel(ii) methanol tetrasolvate trihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343792/ https://www.ncbi.nlm.nih.gov/pubmed/22589766 http://dx.doi.org/10.1107/S1600536812008987 |
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