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Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate

In the title complex, [Ni(2)(C(14)H(17)NO(4))(2)(C(12)H(8)N(2))(2)]·4CH(3)OH·3H(2)O, the two Ni(II) ions are bridged by two Schiff base anions, leading to a dinuclear complex. One Ni(II) ion is six-coordinated by four O atoms and two N atoms of two tridentate Schiff base ligands derived from the con...

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Autores principales: Li, Yan, Guo, Zhenghua, Dong, Jianfang, Li, Lianzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343792/
https://www.ncbi.nlm.nih.gov/pubmed/22589766
http://dx.doi.org/10.1107/S1600536812008987
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author Li, Yan
Guo, Zhenghua
Dong, Jianfang
Li, Lianzhi
author_facet Li, Yan
Guo, Zhenghua
Dong, Jianfang
Li, Lianzhi
author_sort Li, Yan
collection PubMed
description In the title complex, [Ni(2)(C(14)H(17)NO(4))(2)(C(12)H(8)N(2))(2)]·4CH(3)OH·3H(2)O, the two Ni(II) ions are bridged by two Schiff base anions, leading to a dinuclear complex. One Ni(II) ion is six-coordinated by four O atoms and two N atoms of two tridentate Schiff base ligands derived from the condensation of l-isoleucine and o-vanillin. The other Ni(II) ion is six-coordinated by four N atoms of two 1,10-phenanthroline ligands and two O atoms of the Schiff base ligands. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds lead to a three-dimensional structure. Intra­molecular C—H⋯O hydrogen bonds are also present. One of the methyl groups of the l-isoleucinate moieties is disordered over two sets of sites with an occupancy ratio of 0.687 (19):0.313 (19) and two methanol mol­ecules are half-occupied.
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spelling pubmed-33437922012-05-15 Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate Li, Yan Guo, Zhenghua Dong, Jianfang Li, Lianzhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(2)(C(14)H(17)NO(4))(2)(C(12)H(8)N(2))(2)]·4CH(3)OH·3H(2)O, the two Ni(II) ions are bridged by two Schiff base anions, leading to a dinuclear complex. One Ni(II) ion is six-coordinated by four O atoms and two N atoms of two tridentate Schiff base ligands derived from the condensation of l-isoleucine and o-vanillin. The other Ni(II) ion is six-coordinated by four N atoms of two 1,10-phenanthroline ligands and two O atoms of the Schiff base ligands. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds lead to a three-dimensional structure. Intra­molecular C—H⋯O hydrogen bonds are also present. One of the methyl groups of the l-isoleucinate moieties is disordered over two sets of sites with an occupancy ratio of 0.687 (19):0.313 (19) and two methanol mol­ecules are half-occupied. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343792/ /pubmed/22589766 http://dx.doi.org/10.1107/S1600536812008987 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yan
Guo, Zhenghua
Dong, Jianfang
Li, Lianzhi
Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate
title Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate
title_full Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate
title_fullStr Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate
title_full_unstemmed Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate
title_short Bis[μ-N-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) O (2):O (2))-l-isoleucinato-2κ(2) N,O]bis­(1,10-phenanthroline-1κ(2) N,N′)dinickel(II) methanol tetra­solvate trihydrate
title_sort bis[μ-n-(3-meth­oxy-2-oxidobenzyl­idene-1:2κ(2) o (2):o (2))-l-isoleucinato-2κ(2) n,o]bis­(1,10-phenanthroline-1κ(2) n,n′)dinickel(ii) methanol tetra­solvate trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343792/
https://www.ncbi.nlm.nih.gov/pubmed/22589766
http://dx.doi.org/10.1107/S1600536812008987
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