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Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))cobalt(II) trihydrate
In the title compound, [Co(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Co(II) cation, located on an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. Only one carboxy group...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343793/ https://www.ncbi.nlm.nih.gov/pubmed/22589767 http://dx.doi.org/10.1107/S1600536812008902 |
Sumario: | In the title compound, [Co(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Co(II) cation, located on an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. Only one carboxy group of the anion is deprotonated, and the two carboxyl groups of the same anion are linked via an intramolecular O—H⋯O hydrogen bond. One of the lattice water molecules is located on an inversion center, its H atom equally disordered over two positions. One of H atoms of another lattice water molecules is also equally disordered over two sites. Water H atoms and the amino H atom all are involved in an intermolecular hydrogen-bonded network in the crystal. |
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