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Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) trihydrate

In the title compound, [Co(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Co(II) cation, located on an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water mol­ecules in a distorted octa­hedral geometry. Only one carboxy group...

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Autores principales: Miao, Dong-Liang, Li, Shi-Jie, Song, Wen-Dong, Tong, Shao-Wei, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343793/
https://www.ncbi.nlm.nih.gov/pubmed/22589767
http://dx.doi.org/10.1107/S1600536812008902
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author Miao, Dong-Liang
Li, Shi-Jie
Song, Wen-Dong
Tong, Shao-Wei
Ng, Seik Weng
author_facet Miao, Dong-Liang
Li, Shi-Jie
Song, Wen-Dong
Tong, Shao-Wei
Ng, Seik Weng
author_sort Miao, Dong-Liang
collection PubMed
description In the title compound, [Co(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Co(II) cation, located on an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water mol­ecules in a distorted octa­hedral geometry. Only one carboxy group of the anion is deprotonated, and the two carboxyl groups of the same anion are linked via an intra­molecular O—H⋯O hydrogen bond. One of the lattice water mol­ecules is located on an inversion center, its H atom equally disordered over two positions. One of H atoms of another lattice water mol­ecules is also equally disordered over two sites. Water H atoms and the amino H atom all are involved in an inter­molecular hydrogen-bonded network in the crystal.
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spelling pubmed-33437932012-05-15 Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) trihydrate Miao, Dong-Liang Li, Shi-Jie Song, Wen-Dong Tong, Shao-Wei Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Co(II) cation, located on an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water mol­ecules in a distorted octa­hedral geometry. Only one carboxy group of the anion is deprotonated, and the two carboxyl groups of the same anion are linked via an intra­molecular O—H⋯O hydrogen bond. One of the lattice water mol­ecules is located on an inversion center, its H atom equally disordered over two positions. One of H atoms of another lattice water mol­ecules is also equally disordered over two sites. Water H atoms and the amino H atom all are involved in an inter­molecular hydrogen-bonded network in the crystal. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343793/ /pubmed/22589767 http://dx.doi.org/10.1107/S1600536812008902 Text en © Miao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Dong-Liang
Li, Shi-Jie
Song, Wen-Dong
Tong, Shao-Wei
Ng, Seik Weng
Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) trihydrate
title Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) trihydrate
title_full Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) trihydrate
title_fullStr Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) trihydrate
title_full_unstemmed Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) trihydrate
title_short Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) trihydrate
title_sort diaqua­bis­(5-carb­oxy-2-ethyl-1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))cobalt(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343793/
https://www.ncbi.nlm.nih.gov/pubmed/22589767
http://dx.doi.org/10.1107/S1600536812008902
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