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Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))cobalt(II) trihydrate
In the title compound, [Co(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Co(II) cation, located on an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. Only one carboxy group...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343793/ https://www.ncbi.nlm.nih.gov/pubmed/22589767 http://dx.doi.org/10.1107/S1600536812008902 |
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author | Miao, Dong-Liang Li, Shi-Jie Song, Wen-Dong Tong, Shao-Wei Ng, Seik Weng |
author_facet | Miao, Dong-Liang Li, Shi-Jie Song, Wen-Dong Tong, Shao-Wei Ng, Seik Weng |
author_sort | Miao, Dong-Liang |
collection | PubMed |
description | In the title compound, [Co(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Co(II) cation, located on an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. Only one carboxy group of the anion is deprotonated, and the two carboxyl groups of the same anion are linked via an intramolecular O—H⋯O hydrogen bond. One of the lattice water molecules is located on an inversion center, its H atom equally disordered over two positions. One of H atoms of another lattice water molecules is also equally disordered over two sites. Water H atoms and the amino H atom all are involved in an intermolecular hydrogen-bonded network in the crystal. |
format | Online Article Text |
id | pubmed-3343793 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33437932012-05-15 Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))cobalt(II) trihydrate Miao, Dong-Liang Li, Shi-Jie Song, Wen-Dong Tong, Shao-Wei Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Co(II) cation, located on an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. Only one carboxy group of the anion is deprotonated, and the two carboxyl groups of the same anion are linked via an intramolecular O—H⋯O hydrogen bond. One of the lattice water molecules is located on an inversion center, its H atom equally disordered over two positions. One of H atoms of another lattice water molecules is also equally disordered over two sites. Water H atoms and the amino H atom all are involved in an intermolecular hydrogen-bonded network in the crystal. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343793/ /pubmed/22589767 http://dx.doi.org/10.1107/S1600536812008902 Text en © Miao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Miao, Dong-Liang Li, Shi-Jie Song, Wen-Dong Tong, Shao-Wei Ng, Seik Weng Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))cobalt(II) trihydrate |
title | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) trihydrate |
title_full | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) trihydrate |
title_fullStr | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) trihydrate |
title_full_unstemmed | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) trihydrate |
title_short | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))cobalt(II) trihydrate |
title_sort | diaquabis(5-carboxy-2-ethyl-1h-imidazole-4-carboxylato-κ(2)
n
(3),o
(4))cobalt(ii) trihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343793/ https://www.ncbi.nlm.nih.gov/pubmed/22589767 http://dx.doi.org/10.1107/S1600536812008902 |
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