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Dichloridotetrakis(1H-1,2,4-triazole-κN (4))copper(II)
The central Cu(II) atom of the molecular title complex, [CuCl(2)(C(2)H(3)N(3))(4)], is situated on a site with symmetry 2.22. It is six-coordinated in an elongated octahedral geometry, with the equatorial plane defined by four N atoms of four 1,2,4-triazole ligands and the axial positions occupied...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343794/ https://www.ncbi.nlm.nih.gov/pubmed/22589768 http://dx.doi.org/10.1107/S1600536812008872 |
| _version_ | 1782231845932367872 |
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| author | Vidmar, Maja Kobal, Tatjana Kozlevčar, Bojan Šegedin, Primož Golobič, Amalija |
| author_facet | Vidmar, Maja Kobal, Tatjana Kozlevčar, Bojan Šegedin, Primož Golobič, Amalija |
| author_sort | Vidmar, Maja |
| collection | PubMed |
| description | The central Cu(II) atom of the molecular title complex, [CuCl(2)(C(2)H(3)N(3))(4)], is situated on a site with symmetry 2.22. It is six-coordinated in an elongated octahedral geometry, with the equatorial plane defined by four N atoms of four 1,2,4-triazole ligands and the axial positions occupied by two Cl atoms situated on a twofold axis. The molecules are connected via N—H⋯Cl hydrogen bonds and the crystal consists of two interpenetrating three-dimensional hydrogen-bonded frameworks. |
| format | Online Article Text |
| id | pubmed-3343794 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33437942012-05-15 Dichloridotetrakis(1H-1,2,4-triazole-κN (4))copper(II) Vidmar, Maja Kobal, Tatjana Kozlevčar, Bojan Šegedin, Primož Golobič, Amalija Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The central Cu(II) atom of the molecular title complex, [CuCl(2)(C(2)H(3)N(3))(4)], is situated on a site with symmetry 2.22. It is six-coordinated in an elongated octahedral geometry, with the equatorial plane defined by four N atoms of four 1,2,4-triazole ligands and the axial positions occupied by two Cl atoms situated on a twofold axis. The molecules are connected via N—H⋯Cl hydrogen bonds and the crystal consists of two interpenetrating three-dimensional hydrogen-bonded frameworks. International Union of Crystallography 2012-03-03 /pmc/articles/PMC3343794/ /pubmed/22589768 http://dx.doi.org/10.1107/S1600536812008872 Text en © Vidmar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Vidmar, Maja Kobal, Tatjana Kozlevčar, Bojan Šegedin, Primož Golobič, Amalija Dichloridotetrakis(1H-1,2,4-triazole-κN (4))copper(II) |
| title | Dichloridotetrakis(1H-1,2,4-triazole-κN
(4))copper(II) |
| title_full | Dichloridotetrakis(1H-1,2,4-triazole-κN
(4))copper(II) |
| title_fullStr | Dichloridotetrakis(1H-1,2,4-triazole-κN
(4))copper(II) |
| title_full_unstemmed | Dichloridotetrakis(1H-1,2,4-triazole-κN
(4))copper(II) |
| title_short | Dichloridotetrakis(1H-1,2,4-triazole-κN
(4))copper(II) |
| title_sort | dichloridotetrakis(1h-1,2,4-triazole-κn
(4))copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343794/ https://www.ncbi.nlm.nih.gov/pubmed/22589768 http://dx.doi.org/10.1107/S1600536812008872 |
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