Poly[μ(2)-aqua-bis­[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]­dipotassium]

In the title compound, [K(2)(C(8)H(6)N(3)O(2))(2)(H(2)O)](n), each K(+) ion is seven-coordinated by one O atom from a bridging water mol­ecule, five carboxyl­ate O atoms and one N atom from a benzotriazole group, forming a distorted mono-capped octa­hedral geometry. In the crystal, the carboxyl­ate...

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Detalles Bibliográficos
Autor principal: Liu, Qiong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343796/
https://www.ncbi.nlm.nih.gov/pubmed/22589770
http://dx.doi.org/10.1107/S1600536812008963
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author Liu, Qiong
author_facet Liu, Qiong
author_sort Liu, Qiong
collection PubMed
description In the title compound, [K(2)(C(8)H(6)N(3)O(2))(2)(H(2)O)](n), each K(+) ion is seven-coordinated by one O atom from a bridging water mol­ecule, five carboxyl­ate O atoms and one N atom from a benzotriazole group, forming a distorted mono-capped octa­hedral geometry. In the crystal, the carboxyl­ate groups act as bridging ligands, forming a two-dimensional polymer parallel to (001). The aqua ligand, which lies on a twofold rotation axis, forms inter­molecular O—H⋯O hydrogen bonds within these layers.
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spelling pubmed-33437962012-05-15 Poly[μ(2)-aqua-bis­[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]­dipotassium] Liu, Qiong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [K(2)(C(8)H(6)N(3)O(2))(2)(H(2)O)](n), each K(+) ion is seven-coordinated by one O atom from a bridging water mol­ecule, five carboxyl­ate O atoms and one N atom from a benzotriazole group, forming a distorted mono-capped octa­hedral geometry. In the crystal, the carboxyl­ate groups act as bridging ligands, forming a two-dimensional polymer parallel to (001). The aqua ligand, which lies on a twofold rotation axis, forms inter­molecular O—H⋯O hydrogen bonds within these layers. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343796/ /pubmed/22589770 http://dx.doi.org/10.1107/S1600536812008963 Text en © Qiong Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Qiong
Poly[μ(2)-aqua-bis­[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]­dipotassium]
title Poly[μ(2)-aqua-bis­[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]­dipotassium]
title_full Poly[μ(2)-aqua-bis­[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]­dipotassium]
title_fullStr Poly[μ(2)-aqua-bis­[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]­dipotassium]
title_full_unstemmed Poly[μ(2)-aqua-bis­[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]­dipotassium]
title_short Poly[μ(2)-aqua-bis­[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]­dipotassium]
title_sort poly[μ(2)-aqua-bis­[μ(4)-2-(1h-1,2,3-benzotriazol-1-yl)acetato]­dipotassium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343796/
https://www.ncbi.nlm.nih.gov/pubmed/22589770
http://dx.doi.org/10.1107/S1600536812008963
work_keys_str_mv AT liuqiong polym2aquabism421h123benzotriazol1ylacetatodipotassium

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