Dichlorido[2-(phenyl­imino­meth­yl)quinoline-N,N′]palladium(II)

In the title complex, [PdCl(2)(C(16)H(12)N(2))], the Pd(II) ion is coordinated by two N atoms [Pd—N 2.039 (2), 2.073 (2) Å] from a bidentate ligand and two chloride anions [Pd—Cl 2.2655 (7), 2.2991 (7) Å] in a distorted square-planar geometry. In the crystal, π–π inter­actions between the six-member...

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Autores principales: Motswainyana, William M., Onani, Martin O., Madiehe, Abram M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343797/
https://www.ncbi.nlm.nih.gov/pubmed/22589771
http://dx.doi.org/10.1107/S1600536812009130
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author Motswainyana, William M.
Onani, Martin O.
Madiehe, Abram M.
author_facet Motswainyana, William M.
Onani, Martin O.
Madiehe, Abram M.
author_sort Motswainyana, William M.
collection PubMed
description In the title complex, [PdCl(2)(C(16)H(12)N(2))], the Pd(II) ion is coordinated by two N atoms [Pd—N 2.039 (2), 2.073 (2) Å] from a bidentate ligand and two chloride anions [Pd—Cl 2.2655 (7), 2.2991 (7) Å] in a distorted square-planar geometry. In the crystal, π–π inter­actions between the six-membered rings of the quinoline fragments [centroid–centroid distances = 3.815 (5), 3.824 (5) Å] link two mol­ecules into centrosymmetric dimers.
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spelling pubmed-33437972012-05-15 Dichlorido[2-(phenyl­imino­meth­yl)quinoline-N,N′]palladium(II) Motswainyana, William M. Onani, Martin O. Madiehe, Abram M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdCl(2)(C(16)H(12)N(2))], the Pd(II) ion is coordinated by two N atoms [Pd—N 2.039 (2), 2.073 (2) Å] from a bidentate ligand and two chloride anions [Pd—Cl 2.2655 (7), 2.2991 (7) Å] in a distorted square-planar geometry. In the crystal, π–π inter­actions between the six-membered rings of the quinoline fragments [centroid–centroid distances = 3.815 (5), 3.824 (5) Å] link two mol­ecules into centrosymmetric dimers. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343797/ /pubmed/22589771 http://dx.doi.org/10.1107/S1600536812009130 Text en © Motswainyana et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Motswainyana, William M.
Onani, Martin O.
Madiehe, Abram M.
Dichlorido[2-(phenyl­imino­meth­yl)quinoline-N,N′]palladium(II)
title Dichlorido[2-(phenyl­imino­meth­yl)quinoline-N,N′]palladium(II)
title_full Dichlorido[2-(phenyl­imino­meth­yl)quinoline-N,N′]palladium(II)
title_fullStr Dichlorido[2-(phenyl­imino­meth­yl)quinoline-N,N′]palladium(II)
title_full_unstemmed Dichlorido[2-(phenyl­imino­meth­yl)quinoline-N,N′]palladium(II)
title_short Dichlorido[2-(phenyl­imino­meth­yl)quinoline-N,N′]palladium(II)
title_sort dichlorido[2-(phenyl­imino­meth­yl)quinoline-n,n′]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343797/
https://www.ncbi.nlm.nih.gov/pubmed/22589771
http://dx.doi.org/10.1107/S1600536812009130
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