rac-{[2-(Diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate

2-(Diphenyl­thio­phosphino)dimethyl­amino­methyl­ferrocene is a key inter­mediate in the synthesis of various ferrocenyl ligands. During one such synthesis, the title compound, [Fe(C(5)H(5))(C(20)H(22)NPS)](C(12)H(10)PS(2)), was isolated as a by-product. It is built up by association of (2-(diphenyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Mouas, Nardjes, Merazig, Hocine, Daran, Jean-Claude, Manoury, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343798/
https://www.ncbi.nlm.nih.gov/pubmed/22589772
http://dx.doi.org/10.1107/S1600536812009129
_version_ 1782231846884474880
author Mouas, Nardjes
Merazig, Hocine
Daran, Jean-Claude
Manoury, Eric
author_facet Mouas, Nardjes
Merazig, Hocine
Daran, Jean-Claude
Manoury, Eric
author_sort Mouas, Nardjes
collection PubMed
description 2-(Diphenyl­thio­phosphino)dimethyl­amino­methyl­ferrocene is a key inter­mediate in the synthesis of various ferrocenyl ligands. During one such synthesis, the title compound, [Fe(C(5)H(5))(C(20)H(22)NPS)](C(12)H(10)PS(2)), was isolated as a by-product. It is built up by association of (2-(diphenyl­phosphino)ferrocen­yl)meth­yl)dimethyl­ammonium cations and diphenyl­phosphino dithio­ate anions. N—H⋯S, C—H⋯S and C—H⋯π inter­actions link the anions and cations. Each anion–cation pair is linked two by two through C—H⋯π inter­actions, forming pseudo dimers.
format Online
Article
Text
id pubmed-3343798
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33437982012-05-15 rac-{[2-(Diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate Mouas, Nardjes Merazig, Hocine Daran, Jean-Claude Manoury, Eric Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers 2-(Diphenyl­thio­phosphino)dimethyl­amino­methyl­ferrocene is a key inter­mediate in the synthesis of various ferrocenyl ligands. During one such synthesis, the title compound, [Fe(C(5)H(5))(C(20)H(22)NPS)](C(12)H(10)PS(2)), was isolated as a by-product. It is built up by association of (2-(diphenyl­phosphino)ferrocen­yl)meth­yl)dimethyl­ammonium cations and diphenyl­phosphino dithio­ate anions. N—H⋯S, C—H⋯S and C—H⋯π inter­actions link the anions and cations. Each anion–cation pair is linked two by two through C—H⋯π inter­actions, forming pseudo dimers. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343798/ /pubmed/22589772 http://dx.doi.org/10.1107/S1600536812009129 Text en © Mouas et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mouas, Nardjes
Merazig, Hocine
Daran, Jean-Claude
Manoury, Eric
rac-{[2-(Diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate
title rac-{[2-(Diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate
title_full rac-{[2-(Diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate
title_fullStr rac-{[2-(Diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate
title_full_unstemmed rac-{[2-(Diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate
title_short rac-{[2-(Diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate
title_sort rac-{[2-(diphenyl­thio­phosphor­yl)ferrocen­yl]meth­yl}dimethyl­ammonium diphenyl­dithio­phosphinate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343798/
https://www.ncbi.nlm.nih.gov/pubmed/22589772
http://dx.doi.org/10.1107/S1600536812009129
work_keys_str_mv AT mouasnardjes rac2diphenylthiophosphorylferrocenylmethyldimethylammoniumdiphenyldithiophosphinate
AT merazighocine rac2diphenylthiophosphorylferrocenylmethyldimethylammoniumdiphenyldithiophosphinate
AT daranjeanclaude rac2diphenylthiophosphorylferrocenylmethyldimethylammoniumdiphenyldithiophosphinate
AT manouryeric rac2diphenylthiophosphorylferrocenylmethyldimethylammoniumdiphenyldithiophosphinate

Ejemplares similares