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Aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)chromium(III)
In the title compound, [Cr(C(7)H(2)N(2)O(7))Cl(C(12)H(8)N(2))(H(2)O)], the Cr(III) atom displays a distorted octahedral coordination geometry, with the chelating phenantroline and 3,5-dinitrosalicylate ligands in trans positions. In the crystal, molecules are connected via O—H⋯O hydrogen bonds in...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343802/ https://www.ncbi.nlm.nih.gov/pubmed/22589776 http://dx.doi.org/10.1107/S1600536812009324 |
| _version_ | 1782231847885864960 |
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| author | Meng, Zhao-Hui Lian, Hui Zhang, Shu-Shen Feng, Yu-Quan |
| author_facet | Meng, Zhao-Hui Lian, Hui Zhang, Shu-Shen Feng, Yu-Quan |
| author_sort | Meng, Zhao-Hui |
| collection | PubMed |
| description | In the title compound, [Cr(C(7)H(2)N(2)O(7))Cl(C(12)H(8)N(2))(H(2)O)], the Cr(III) atom displays a distorted octahedral coordination geometry, with the chelating phenantroline and 3,5-dinitrosalicylate ligands in trans positions. In the crystal, molecules are connected via O—H⋯O hydrogen bonds into a two-dimensional framework parallel to (100). In addition, there are π–π stacking interactions between phenanthroline ligands along the c axis, with a mean interplanar distance of 3.456 (4) Å. |
| format | Online Article Text |
| id | pubmed-3343802 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438022012-05-15 Aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)chromium(III) Meng, Zhao-Hui Lian, Hui Zhang, Shu-Shen Feng, Yu-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cr(C(7)H(2)N(2)O(7))Cl(C(12)H(8)N(2))(H(2)O)], the Cr(III) atom displays a distorted octahedral coordination geometry, with the chelating phenantroline and 3,5-dinitrosalicylate ligands in trans positions. In the crystal, molecules are connected via O—H⋯O hydrogen bonds into a two-dimensional framework parallel to (100). In addition, there are π–π stacking interactions between phenanthroline ligands along the c axis, with a mean interplanar distance of 3.456 (4) Å. International Union of Crystallography 2012-03-07 /pmc/articles/PMC3343802/ /pubmed/22589776 http://dx.doi.org/10.1107/S1600536812009324 Text en © Meng et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Meng, Zhao-Hui Lian, Hui Zhang, Shu-Shen Feng, Yu-Quan Aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)chromium(III) |
| title | Aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)chromium(III) |
| title_full | Aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)chromium(III) |
| title_fullStr | Aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)chromium(III) |
| title_full_unstemmed | Aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)chromium(III) |
| title_short | Aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)chromium(III) |
| title_sort | aquachlorido(3,5-dinitro-2-oxidobenzoato-κ(2)
o
(1),o
(2))(1,10-phenanthroline-κ(2)
n,n′)chromium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343802/ https://www.ncbi.nlm.nih.gov/pubmed/22589776 http://dx.doi.org/10.1107/S1600536812009324 |
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