Bis{S-benzyl 3-[(phen­yl)(pyridin-2-yl)methyl­idene]dithio­carbazato}zinc acetonitrile monosolvate

In the title compound, [Zn(C(20)H(16)N(3)S(2))(2)]·CH(3)CN, two different Schiff base moieties coordinate to the central Zn(II) ion as tridentate N,N′,S-chelating ligands, creating a distorted octa­hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with...

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Detalles Bibliográficos
Autores principales: Ravoof, Thahira B. S. A., Omar, Siti Aminah, Mohamed Tahir, Mohamed Ibrahim, Crouse, Karen A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343804/
https://www.ncbi.nlm.nih.gov/pubmed/22589778
http://dx.doi.org/10.1107/S1600536812009592
Descripción
Sumario:In the title compound, [Zn(C(20)H(16)N(3)S(2))(2)]·CH(3)CN, two different Schiff base moieties coordinate to the central Zn(II) ion as tridentate N,N′,S-chelating ligands, creating a distorted octa­hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H⋯N hydrogen-bonding inter­actions.

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