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{4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II)
In the title compound, [Cu(C(19)H(16)Br(4)N(2)O(2))], the Cu(II) ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) ion is distorted square-planar, which is defined by the N(2)O(2) donor atoms of the coordinated Schi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343805/ https://www.ncbi.nlm.nih.gov/pubmed/22589779 http://dx.doi.org/10.1107/S1600536812009397 |
| _version_ | 1782231848597848064 |
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| author | Kargar, Hadi Kia, Reza Haghshenas, Mahbubeh Tahir, Muhammad Nawaz |
| author_facet | Kargar, Hadi Kia, Reza Haghshenas, Mahbubeh Tahir, Muhammad Nawaz |
| author_sort | Kargar, Hadi |
| collection | PubMed |
| description | In the title compound, [Cu(C(19)H(16)Br(4)N(2)O(2))], the Cu(II) ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) ion is distorted square-planar, which is defined by the N(2)O(2) donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an intermolecular π–π interaction [centroid–centroid distance = 3.8891 (18) Å]. |
| format | Online Article Text |
| id | pubmed-3343805 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438052012-05-15 {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) Kargar, Hadi Kia, Reza Haghshenas, Mahbubeh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(19)H(16)Br(4)N(2)O(2))], the Cu(II) ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) ion is distorted square-planar, which is defined by the N(2)O(2) donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an intermolecular π–π interaction [centroid–centroid distance = 3.8891 (18) Å]. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343805/ /pubmed/22589779 http://dx.doi.org/10.1107/S1600536812009397 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kargar, Hadi Kia, Reza Haghshenas, Mahbubeh Tahir, Muhammad Nawaz {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_full | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_fullStr | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_full_unstemmed | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_short | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_sort | {4,4′,6,6′-tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343805/ https://www.ncbi.nlm.nih.gov/pubmed/22589779 http://dx.doi.org/10.1107/S1600536812009397 |
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