(Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate

The title compound, [Rh(C(5)H(7)O(2))(C(30)H(21)P)(CO)]·0.5C(3)H(6)O, has two different complex molecules in the asymmetric unit, with the Rh(I) atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol­ecules with one acetone solvent mol­ecul...

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Detalles Bibliográficos
Autores principales: Ogutu, Hezron, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343806/
https://www.ncbi.nlm.nih.gov/pubmed/22589780
http://dx.doi.org/10.1107/S1600536812008148
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author Ogutu, Hezron
Meijboom, Reinout
author_facet Ogutu, Hezron
Meijboom, Reinout
author_sort Ogutu, Hezron
collection PubMed
description The title compound, [Rh(C(5)H(7)O(2))(C(30)H(21)P)(CO)]·0.5C(3)H(6)O, has two different complex molecules in the asymmetric unit, with the Rh(I) atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol­ecules with one acetone solvent mol­ecule sitting at the centre.
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spelling pubmed-33438062012-05-15 (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate Ogutu, Hezron Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Rh(C(5)H(7)O(2))(C(30)H(21)P)(CO)]·0.5C(3)H(6)O, has two different complex molecules in the asymmetric unit, with the Rh(I) atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol­ecules with one acetone solvent mol­ecule sitting at the centre. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343806/ /pubmed/22589780 http://dx.doi.org/10.1107/S1600536812008148 Text en © Ogutu and Meijboom 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ogutu, Hezron
Meijboom, Reinout
(Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate
title (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate
title_full (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate
title_fullStr (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate
title_full_unstemmed (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate
title_short (Acetyl­acetonato-κ(2) O,O′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate
title_sort (acetyl­acetonato-κ(2) o,o′)carbon­yl[tris­(naphthalen-1-yl)phosphane-κp]rhodium(i) acetone hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343806/
https://www.ncbi.nlm.nih.gov/pubmed/22589780
http://dx.doi.org/10.1107/S1600536812008148
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AT meijboomreinout acetylacetonatok2oocarbonyltrisnaphthalen1ylphosphanekprhodiumiacetonehemisolvate

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