Bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)

The asymmetric unit of the title complex, (C(9)H(15)N(2))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 4-dimethyl­amino-1-ethyl­pyri­din­ium cation and one half of a [Ni(mnt)(2)](2−) (mnt(2−) = maleo­nitrile­dithiol­ate) anion; the complete anion is generated by the application of a centre of inversion. T...

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Detalles Bibliográficos
Autores principales: Yu, Shan-Shan, Zhou, Hong, Ren, Xiao-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343807/
https://www.ncbi.nlm.nih.gov/pubmed/22589781
http://dx.doi.org/10.1107/S1600536812008161
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author Yu, Shan-Shan
Zhou, Hong
Ren, Xiao-Ming
author_facet Yu, Shan-Shan
Zhou, Hong
Ren, Xiao-Ming
author_sort Yu, Shan-Shan
collection PubMed
description The asymmetric unit of the title complex, (C(9)H(15)N(2))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 4-dimethyl­amino-1-ethyl­pyri­din­ium cation and one half of a [Ni(mnt)(2)](2−) (mnt(2−) = maleo­nitrile­dithiol­ate) anion; the complete anion is generated by the application of a centre of inversion. The Ni(II) ion is coordinated by four S atoms of two mnt(2−) ligands and exhibits a square-planar coordination geometry.
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spelling pubmed-33438072012-05-15 Bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II) Yu, Shan-Shan Zhou, Hong Ren, Xiao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, (C(9)H(15)N(2))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 4-dimethyl­amino-1-ethyl­pyri­din­ium cation and one half of a [Ni(mnt)(2)](2−) (mnt(2−) = maleo­nitrile­dithiol­ate) anion; the complete anion is generated by the application of a centre of inversion. The Ni(II) ion is coordinated by four S atoms of two mnt(2−) ligands and exhibits a square-planar coordination geometry. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343807/ /pubmed/22589781 http://dx.doi.org/10.1107/S1600536812008161 Text en © Yu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Shan-Shan
Zhou, Hong
Ren, Xiao-Ming
Bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title Bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_full Bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_fullStr Bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_full_unstemmed Bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_short Bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)
title_sort bis(4-dimethyl­amino-1-ethyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) s,s′)nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343807/
https://www.ncbi.nlm.nih.gov/pubmed/22589781
http://dx.doi.org/10.1107/S1600536812008161
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AT zhouhong bis4dimethylamino1ethylpyridiniumbis12dicyanoethene12dithiolatok2ssnickelateii
AT renxiaoming bis4dimethylamino1ethylpyridiniumbis12dicyanoethene12dithiolatok2ssnickelateii

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