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Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate

In the title compound, [Cd(C(2)H(8)N(2))(3)](GeF(6)), the Cd(II) atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethyl­enediamine (en) ligands in a distorted octa­hedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand...

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Detalles Bibliográficos
Autores principales: Wang, Guo-Ming, Li, Zeng-Xin, Wang, Pei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343808/
https://www.ncbi.nlm.nih.gov/pubmed/22589782
http://dx.doi.org/10.1107/S160053681200983X
Descripción
Sumario:In the title compound, [Cd(C(2)H(8)N(2))(3)](GeF(6)), the Cd(II) atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethyl­enediamine (en) ligands in a distorted octa­hedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)(3)](2+) cations and [GeF(6)](2−) anions are connected through N—H⋯F hydrogen bonds, forming a three-dimensional supra­molecular network.