Cargando…
Tris(ethylenediamine-κ(2) N,N′)cadmium hexafluoridogermanate
In the title compound, [Cd(C(2)H(8)N(2))(3)](GeF(6)), the Cd(II) atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343808/ https://www.ncbi.nlm.nih.gov/pubmed/22589782 http://dx.doi.org/10.1107/S160053681200983X |
_version_ | 1782231849310879744 |
---|---|
author | Wang, Guo-Ming Li, Zeng-Xin Wang, Pei |
author_facet | Wang, Guo-Ming Li, Zeng-Xin Wang, Pei |
author_sort | Wang, Guo-Ming |
collection | PubMed |
description | In the title compound, [Cd(C(2)H(8)N(2))(3)](GeF(6)), the Cd(II) atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)(3)](2+) cations and [GeF(6)](2−) anions are connected through N—H⋯F hydrogen bonds, forming a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3343808 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438082012-05-15 Tris(ethylenediamine-κ(2) N,N′)cadmium hexafluoridogermanate Wang, Guo-Ming Li, Zeng-Xin Wang, Pei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(2)H(8)N(2))(3)](GeF(6)), the Cd(II) atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)(3)](2+) cations and [GeF(6)](2−) anions are connected through N—H⋯F hydrogen bonds, forming a three-dimensional supramolecular network. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343808/ /pubmed/22589782 http://dx.doi.org/10.1107/S160053681200983X Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Guo-Ming Li, Zeng-Xin Wang, Pei Tris(ethylenediamine-κ(2) N,N′)cadmium hexafluoridogermanate |
title | Tris(ethylenediamine-κ(2)
N,N′)cadmium hexafluoridogermanate |
title_full | Tris(ethylenediamine-κ(2)
N,N′)cadmium hexafluoridogermanate |
title_fullStr | Tris(ethylenediamine-κ(2)
N,N′)cadmium hexafluoridogermanate |
title_full_unstemmed | Tris(ethylenediamine-κ(2)
N,N′)cadmium hexafluoridogermanate |
title_short | Tris(ethylenediamine-κ(2)
N,N′)cadmium hexafluoridogermanate |
title_sort | tris(ethylenediamine-κ(2)
n,n′)cadmium hexafluoridogermanate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343808/ https://www.ncbi.nlm.nih.gov/pubmed/22589782 http://dx.doi.org/10.1107/S160053681200983X |
work_keys_str_mv | AT wangguoming trisethylenediaminek2nncadmiumhexafluoridogermanate AT lizengxin trisethylenediaminek2nncadmiumhexafluoridogermanate AT wangpei trisethylenediaminek2nncadmiumhexafluoridogermanate |