Cargando…

Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate

In the title compound, [Cd(C(2)H(8)N(2))(3)](GeF(6)), the Cd(II) atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethyl­enediamine (en) ligands in a distorted octa­hedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Guo-Ming, Li, Zeng-Xin, Wang, Pei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343808/
https://www.ncbi.nlm.nih.gov/pubmed/22589782
http://dx.doi.org/10.1107/S160053681200983X
_version_ 1782231849310879744
author Wang, Guo-Ming
Li, Zeng-Xin
Wang, Pei
author_facet Wang, Guo-Ming
Li, Zeng-Xin
Wang, Pei
author_sort Wang, Guo-Ming
collection PubMed
description In the title compound, [Cd(C(2)H(8)N(2))(3)](GeF(6)), the Cd(II) atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethyl­enediamine (en) ligands in a distorted octa­hedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)(3)](2+) cations and [GeF(6)](2−) anions are connected through N—H⋯F hydrogen bonds, forming a three-dimensional supra­molecular network.
format Online
Article
Text
id pubmed-3343808
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33438082012-05-15 Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate Wang, Guo-Ming Li, Zeng-Xin Wang, Pei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(2)H(8)N(2))(3)](GeF(6)), the Cd(II) atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethyl­enediamine (en) ligands in a distorted octa­hedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)(3)](2+) cations and [GeF(6)](2−) anions are connected through N—H⋯F hydrogen bonds, forming a three-dimensional supra­molecular network. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343808/ /pubmed/22589782 http://dx.doi.org/10.1107/S160053681200983X Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Guo-Ming
Li, Zeng-Xin
Wang, Pei
Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate
title Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate
title_full Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate
title_fullStr Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate
title_full_unstemmed Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate
title_short Tris(ethyl­enediamine-κ(2) N,N′)cadmium hexa­fluoridogermanate
title_sort tris(ethyl­enediamine-κ(2) n,n′)cadmium hexa­fluoridogermanate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343808/
https://www.ncbi.nlm.nih.gov/pubmed/22589782
http://dx.doi.org/10.1107/S160053681200983X
work_keys_str_mv AT wangguoming trisethylenediaminek2nncadmiumhexafluoridogermanate
AT lizengxin trisethylenediaminek2nncadmiumhexafluoridogermanate
AT wangpei trisethylenediaminek2nncadmiumhexafluoridogermanate