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(Acetato-κO)(aqua-κO)(2-{bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octahedral environment defined by one O and three N atoms derived from the tetradentate ligand, and two O atoms, one from a water molecule and the other from an acetate a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343810/ https://www.ncbi.nlm.nih.gov/pubmed/22589784 http://dx.doi.org/10.1107/S1600536812007970 |
Sumario: | In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octahedral environment defined by one O and three N atoms derived from the tetradentate ligand, and two O atoms, one from a water molecule and the other from an acetate anion. The molecules are connected into a three-dimensional architecture by O—H⋯O hydrogen bonds. The perchlorate anion is disordered over two positions; the major component has a site-occupancy factor of 0.525 (19). |
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