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(Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate

In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octa­hedral environment defined by one O and three N atoms derived from the tetra­dentate ligand, and two O atoms, one from a water mol­ecule and the other from an acetate a...

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Detalles Bibliográficos
Autores principales: Zhou, Jia, Shu, Mouhai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343810/
https://www.ncbi.nlm.nih.gov/pubmed/22589784
http://dx.doi.org/10.1107/S1600536812007970
Descripción
Sumario:In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octa­hedral environment defined by one O and three N atoms derived from the tetra­dentate ligand, and two O atoms, one from a water mol­ecule and the other from an acetate anion. The mol­ecules are connected into a three-dimensional architecture by O—H⋯O hydrogen bonds. The perchlorate anion is disordered over two positions; the major component has a site-occupancy factor of 0.525 (19).