(Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate

In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octa­hedral environment defined by one O and three N atoms derived from the tetra­dentate ligand, and two O atoms, one from a water mol­ecule and the other from an acetate a...

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Detalles Bibliográficos
Autores principales: Zhou, Jia, Shu, Mouhai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343810/
https://www.ncbi.nlm.nih.gov/pubmed/22589784
http://dx.doi.org/10.1107/S1600536812007970
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author Zhou, Jia
Shu, Mouhai
author_facet Zhou, Jia
Shu, Mouhai
author_sort Zhou, Jia
collection PubMed
description In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octa­hedral environment defined by one O and three N atoms derived from the tetra­dentate ligand, and two O atoms, one from a water mol­ecule and the other from an acetate anion. The mol­ecules are connected into a three-dimensional architecture by O—H⋯O hydrogen bonds. The perchlorate anion is disordered over two positions; the major component has a site-occupancy factor of 0.525 (19).
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spelling pubmed-33438102012-05-15 (Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate Zhou, Jia Shu, Mouhai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [Ni(CH(3)CO(2))(C(14)H(23)N(5)O)(H(2)O)]ClO(4)·H(2)O, the Ni(II) centre has a distorted octa­hedral environment defined by one O and three N atoms derived from the tetra­dentate ligand, and two O atoms, one from a water mol­ecule and the other from an acetate anion. The mol­ecules are connected into a three-dimensional architecture by O—H⋯O hydrogen bonds. The perchlorate anion is disordered over two positions; the major component has a site-occupancy factor of 0.525 (19). International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343810/ /pubmed/22589784 http://dx.doi.org/10.1107/S1600536812007970 Text en © Zhou and Shu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Jia
Shu, Mouhai
(Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title (Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_full (Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_fullStr (Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_full_unstemmed (Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_short (Acetato-κO)(aqua-κO)(2-{bis­[(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]amino-κN}ethanol-κO)nickel(II) perchlorate monohydrate
title_sort (acetato-κo)(aqua-κo)(2-{bis­[(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))methyl]amino-κn}ethanol-κo)nickel(ii) perchlorate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343810/
https://www.ncbi.nlm.nih.gov/pubmed/22589784
http://dx.doi.org/10.1107/S1600536812007970
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