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catena-Poly[[[triaqua­cobalt(II)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate]

The polymeric title compound, {[Co(C(15)H(9)NO(4)S)(H(2)O)(3)]·H(2)O}(n), consists of chains along [001] made up from Co(2+) ions bridged by 10-methyl­phenothia­zine-3,7-dicarboxyl­ate anions. The Co(2+) ion, coordinated by three O atoms from two different carboxyl­ate groups and three water mol­ecu...

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Detalles Bibliográficos
Autores principales: Hu, Yun-Xia, Zhou, Yan, Wang, Fang-Ming, Zhang, Wen-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343812/
https://www.ncbi.nlm.nih.gov/pubmed/22589786
http://dx.doi.org/10.1107/S1600536812009580
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author Hu, Yun-Xia
Zhou, Yan
Wang, Fang-Ming
Zhang, Wen-Wei
author_facet Hu, Yun-Xia
Zhou, Yan
Wang, Fang-Ming
Zhang, Wen-Wei
author_sort Hu, Yun-Xia
collection PubMed
description The polymeric title compound, {[Co(C(15)H(9)NO(4)S)(H(2)O)(3)]·H(2)O}(n), consists of chains along [001] made up from Co(2+) ions bridged by 10-methyl­phenothia­zine-3,7-dicarboxyl­ate anions. The Co(2+) ion, coordinated by three O atoms from two different carboxyl­ate groups and three water mol­ecules, displays a distorted octa­hedral environment. In the crystal, π–π inter­chain inter­actions, with centroid–centroid distances of 3.656 (2) and 3.669 (2) Å between the benzene rings of the ligands, assemble the chains into sheets parallel to (100). O—H⋯O hydrogen-bonding inter­actions between the coordinating water mol­ecules and carboxyl­ate O atoms link the sheets into a three-dimensional network.
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spelling pubmed-33438122012-05-15 catena-Poly[[[triaqua­cobalt(II)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate] Hu, Yun-Xia Zhou, Yan Wang, Fang-Ming Zhang, Wen-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The polymeric title compound, {[Co(C(15)H(9)NO(4)S)(H(2)O)(3)]·H(2)O}(n), consists of chains along [001] made up from Co(2+) ions bridged by 10-methyl­phenothia­zine-3,7-dicarboxyl­ate anions. The Co(2+) ion, coordinated by three O atoms from two different carboxyl­ate groups and three water mol­ecules, displays a distorted octa­hedral environment. In the crystal, π–π inter­chain inter­actions, with centroid–centroid distances of 3.656 (2) and 3.669 (2) Å between the benzene rings of the ligands, assemble the chains into sheets parallel to (100). O—H⋯O hydrogen-bonding inter­actions between the coordinating water mol­ecules and carboxyl­ate O atoms link the sheets into a three-dimensional network. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343812/ /pubmed/22589786 http://dx.doi.org/10.1107/S1600536812009580 Text en © Hu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Yun-Xia
Zhou, Yan
Wang, Fang-Ming
Zhang, Wen-Wei
catena-Poly[[[triaqua­cobalt(II)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate]
title catena-Poly[[[triaqua­cobalt(II)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate]
title_full catena-Poly[[[triaqua­cobalt(II)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate]
title_fullStr catena-Poly[[[triaqua­cobalt(II)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate]
title_full_unstemmed catena-Poly[[[triaqua­cobalt(II)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate]
title_short catena-Poly[[[triaqua­cobalt(II)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate]
title_sort catena-poly[[[triaqua­cobalt(ii)]-μ-10-methyl­phenothia­zine-3,7-dicarboxyl­ato] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343812/
https://www.ncbi.nlm.nih.gov/pubmed/22589786
http://dx.doi.org/10.1107/S1600536812009580
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