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catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate]
The polymeric title compound, {[Co(C(15)H(9)NO(4)S)(H(2)O)(3)]·H(2)O}(n), consists of chains along [001] made up from Co(2+) ions bridged by 10-methylphenothiazine-3,7-dicarboxylate anions. The Co(2+) ion, coordinated by three O atoms from two different carboxylate groups and three water molecu...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343812/ https://www.ncbi.nlm.nih.gov/pubmed/22589786 http://dx.doi.org/10.1107/S1600536812009580 |
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author | Hu, Yun-Xia Zhou, Yan Wang, Fang-Ming Zhang, Wen-Wei |
author_facet | Hu, Yun-Xia Zhou, Yan Wang, Fang-Ming Zhang, Wen-Wei |
author_sort | Hu, Yun-Xia |
collection | PubMed |
description | The polymeric title compound, {[Co(C(15)H(9)NO(4)S)(H(2)O)(3)]·H(2)O}(n), consists of chains along [001] made up from Co(2+) ions bridged by 10-methylphenothiazine-3,7-dicarboxylate anions. The Co(2+) ion, coordinated by three O atoms from two different carboxylate groups and three water molecules, displays a distorted octahedral environment. In the crystal, π–π interchain interactions, with centroid–centroid distances of 3.656 (2) and 3.669 (2) Å between the benzene rings of the ligands, assemble the chains into sheets parallel to (100). O—H⋯O hydrogen-bonding interactions between the coordinating water molecules and carboxylate O atoms link the sheets into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3343812 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438122012-05-15 catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate] Hu, Yun-Xia Zhou, Yan Wang, Fang-Ming Zhang, Wen-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The polymeric title compound, {[Co(C(15)H(9)NO(4)S)(H(2)O)(3)]·H(2)O}(n), consists of chains along [001] made up from Co(2+) ions bridged by 10-methylphenothiazine-3,7-dicarboxylate anions. The Co(2+) ion, coordinated by three O atoms from two different carboxylate groups and three water molecules, displays a distorted octahedral environment. In the crystal, π–π interchain interactions, with centroid–centroid distances of 3.656 (2) and 3.669 (2) Å between the benzene rings of the ligands, assemble the chains into sheets parallel to (100). O—H⋯O hydrogen-bonding interactions between the coordinating water molecules and carboxylate O atoms link the sheets into a three-dimensional network. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343812/ /pubmed/22589786 http://dx.doi.org/10.1107/S1600536812009580 Text en © Hu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hu, Yun-Xia Zhou, Yan Wang, Fang-Ming Zhang, Wen-Wei catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate] |
title |
catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate] |
title_full |
catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate] |
title_fullStr |
catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate] |
title_full_unstemmed |
catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate] |
title_short |
catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate] |
title_sort | catena-poly[[[triaquacobalt(ii)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343812/ https://www.ncbi.nlm.nih.gov/pubmed/22589786 http://dx.doi.org/10.1107/S1600536812009580 |
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