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trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II)
The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd—P bond lengths are 2.3343 (5) Å, as the Pd atom lies on an inversion centre, while the Pd—Cl bond lengths are 2.3017 (4) Å. The observed structure was found to be closel...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343813/ https://www.ncbi.nlm.nih.gov/pubmed/22589787 http://dx.doi.org/10.1107/S1600536812010100 |
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author | Burgoyne, Andrew R. Meijboom, Reinout Ogutu, Hezron |
author_facet | Burgoyne, Andrew R. Meijboom, Reinout Ogutu, Hezron |
author_sort | Burgoyne, Andrew R. |
collection | PubMed |
description | The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd—P bond lengths are 2.3343 (5) Å, as the Pd atom lies on an inversion centre, while the Pd—Cl bond lengths are 2.3017 (4) Å. The observed structure was found to be closely related to [PdCl(2){P(C(6)H(11))(3)}(2)] [Grushin et al. (1994 ▶). Inorg. Chem. 33, 4804–4806], [PdBr(2){P(C(6)H(11))(3)}(2)] [Clarke et al. (2003 ▶). Dalton Trans. pp. 4393–4394] and [PdCl(2)P(C(6)H(11))(2)(C(7)H(7))}(2)] [Vuoti et al. (2008 ▶). Eur. J. Inorg. Chem. pp. 397–407] (C(6)H(11) is cyclohexyl and C(7)H(7) is o-tolyl). One of the cyclohexyl rings is disordered with the phenyl ring in a 0.587 (9):413 (9) ratio. Five long-range C—H⋯Cl interactions were observed within the structure. |
format | Online Article Text |
id | pubmed-3343813 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438132012-05-15 trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II) Burgoyne, Andrew R. Meijboom, Reinout Ogutu, Hezron Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd—P bond lengths are 2.3343 (5) Å, as the Pd atom lies on an inversion centre, while the Pd—Cl bond lengths are 2.3017 (4) Å. The observed structure was found to be closely related to [PdCl(2){P(C(6)H(11))(3)}(2)] [Grushin et al. (1994 ▶). Inorg. Chem. 33, 4804–4806], [PdBr(2){P(C(6)H(11))(3)}(2)] [Clarke et al. (2003 ▶). Dalton Trans. pp. 4393–4394] and [PdCl(2)P(C(6)H(11))(2)(C(7)H(7))}(2)] [Vuoti et al. (2008 ▶). Eur. J. Inorg. Chem. pp. 397–407] (C(6)H(11) is cyclohexyl and C(7)H(7) is o-tolyl). One of the cyclohexyl rings is disordered with the phenyl ring in a 0.587 (9):413 (9) ratio. Five long-range C—H⋯Cl interactions were observed within the structure. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343813/ /pubmed/22589787 http://dx.doi.org/10.1107/S1600536812010100 Text en © Burgoyne et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Burgoyne, Andrew R. Meijboom, Reinout Ogutu, Hezron trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II) |
title |
trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II) |
title_full |
trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II) |
title_fullStr |
trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II) |
title_full_unstemmed |
trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II) |
title_short |
trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II) |
title_sort | trans-dichloridobis[dicyclohexyl(phenyl)phosphane-κp]palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343813/ https://www.ncbi.nlm.nih.gov/pubmed/22589787 http://dx.doi.org/10.1107/S1600536812010100 |
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