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trans-Dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II)

The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd—P bond lengths are 2.3343 (5) Å, as the Pd atom lies on an inversion centre, while the Pd—Cl bond lengths are 2.3017 (4) Å. The observed structure was found to be closel...

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Detalles Bibliográficos
Autores principales: Burgoyne, Andrew R., Meijboom, Reinout, Ogutu, Hezron
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343813/
https://www.ncbi.nlm.nih.gov/pubmed/22589787
http://dx.doi.org/10.1107/S1600536812010100
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author Burgoyne, Andrew R.
Meijboom, Reinout
Ogutu, Hezron
author_facet Burgoyne, Andrew R.
Meijboom, Reinout
Ogutu, Hezron
author_sort Burgoyne, Andrew R.
collection PubMed
description The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd—P bond lengths are 2.3343 (5) Å, as the Pd atom lies on an inversion centre, while the Pd—Cl bond lengths are 2.3017 (4) Å. The observed structure was found to be closely related to [PdCl(2){P(C(6)H(11))(3)}(2)] [Grushin et al. (1994 ▶). Inorg. Chem. 33, 4804–4806], [PdBr(2){P(C(6)H(11))(3)}(2)] [Clarke et al. (2003 ▶). Dalton Trans. pp. 4393–4394] and [PdCl(2)P(C(6)H(11))(2)(C(7)H(7))}(2)] [Vuoti et al. (2008 ▶). Eur. J. Inorg. Chem. pp. 397–407] (C(6)H(11) is cyclo­hexyl and C(7)H(7) is o-tol­yl). One of the cyclo­hexyl rings is disordered with the phenyl ring in a 0.587 (9):413 (9) ratio. Five long-range C—H⋯Cl inter­actions were observed within the structure.
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spelling pubmed-33438132012-05-15 trans-Dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II) Burgoyne, Andrew R. Meijboom, Reinout Ogutu, Hezron Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd—P bond lengths are 2.3343 (5) Å, as the Pd atom lies on an inversion centre, while the Pd—Cl bond lengths are 2.3017 (4) Å. The observed structure was found to be closely related to [PdCl(2){P(C(6)H(11))(3)}(2)] [Grushin et al. (1994 ▶). Inorg. Chem. 33, 4804–4806], [PdBr(2){P(C(6)H(11))(3)}(2)] [Clarke et al. (2003 ▶). Dalton Trans. pp. 4393–4394] and [PdCl(2)P(C(6)H(11))(2)(C(7)H(7))}(2)] [Vuoti et al. (2008 ▶). Eur. J. Inorg. Chem. pp. 397–407] (C(6)H(11) is cyclo­hexyl and C(7)H(7) is o-tol­yl). One of the cyclo­hexyl rings is disordered with the phenyl ring in a 0.587 (9):413 (9) ratio. Five long-range C—H⋯Cl inter­actions were observed within the structure. International Union of Crystallography 2012-03-10 /pmc/articles/PMC3343813/ /pubmed/22589787 http://dx.doi.org/10.1107/S1600536812010100 Text en © Burgoyne et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Burgoyne, Andrew R.
Meijboom, Reinout
Ogutu, Hezron
trans-Dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II)
title trans-Dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II)
title_full trans-Dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II)
title_fullStr trans-Dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II)
title_full_unstemmed trans-Dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II)
title_short trans-Dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II)
title_sort trans-dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κp]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343813/
https://www.ncbi.nlm.nih.gov/pubmed/22589787
http://dx.doi.org/10.1107/S1600536812010100
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