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catena-Poly[[tetra­kis­(1H-pyrazole-κN (2))copper(II)]-μ-hexa­fluoridosilicato-κ(2) F:F′]

In the title one-dimensional coordination polymer, [Cu(SiF(6))(C(3)H(4)N(2))(4)](n), the Cu(II) atom is coordinated by two hexafluoridosilicate F atoms and four pyrazole N atoms in a distorted trans-CuF(2)N(4) octa­hedral environment. The dihedral angle between the planes of the pyrazlole rings in t...

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Detalles Bibliográficos
Autores principales: Li, Hui, Han, Qiuping, Chai, Xiaochuan, Wang, Jian, Yao, Chenzhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343814/
https://www.ncbi.nlm.nih.gov/pubmed/22589788
http://dx.doi.org/10.1107/S1600536812009531
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author Li, Hui
Han, Qiuping
Chai, Xiaochuan
Wang, Jian
Yao, Chenzhong
author_facet Li, Hui
Han, Qiuping
Chai, Xiaochuan
Wang, Jian
Yao, Chenzhong
author_sort Li, Hui
collection PubMed
description In the title one-dimensional coordination polymer, [Cu(SiF(6))(C(3)H(4)N(2))(4)](n), the Cu(II) atom is coordinated by two hexafluoridosilicate F atoms and four pyrazole N atoms in a distorted trans-CuF(2)N(4) octa­hedral environment. The dihedral angle between the planes of the pyrazlole rings in the asymmetric unit is 74.4 (3)°. The hexa­fluoridosilicate dianion acts as a bridging ligand, connecting the Cu(II) atoms into a [1-10] chain. The Cu and Si atoms lie on special positions with 2/m site symmetry. In the crystal, intra­chain N—H⋯F hydrogen bonds occur and weak C—H⋯F inter­actions link the chains.
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spelling pubmed-33438142012-05-15 catena-Poly[[tetra­kis­(1H-pyrazole-κN (2))copper(II)]-μ-hexa­fluoridosilicato-κ(2) F:F′] Li, Hui Han, Qiuping Chai, Xiaochuan Wang, Jian Yao, Chenzhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [Cu(SiF(6))(C(3)H(4)N(2))(4)](n), the Cu(II) atom is coordinated by two hexafluoridosilicate F atoms and four pyrazole N atoms in a distorted trans-CuF(2)N(4) octa­hedral environment. The dihedral angle between the planes of the pyrazlole rings in the asymmetric unit is 74.4 (3)°. The hexa­fluoridosilicate dianion acts as a bridging ligand, connecting the Cu(II) atoms into a [1-10] chain. The Cu and Si atoms lie on special positions with 2/m site symmetry. In the crystal, intra­chain N—H⋯F hydrogen bonds occur and weak C—H⋯F inter­actions link the chains. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343814/ /pubmed/22589788 http://dx.doi.org/10.1107/S1600536812009531 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hui
Han, Qiuping
Chai, Xiaochuan
Wang, Jian
Yao, Chenzhong
catena-Poly[[tetra­kis­(1H-pyrazole-κN (2))copper(II)]-μ-hexa­fluoridosilicato-κ(2) F:F′]
title catena-Poly[[tetra­kis­(1H-pyrazole-κN (2))copper(II)]-μ-hexa­fluoridosilicato-κ(2) F:F′]
title_full catena-Poly[[tetra­kis­(1H-pyrazole-κN (2))copper(II)]-μ-hexa­fluoridosilicato-κ(2) F:F′]
title_fullStr catena-Poly[[tetra­kis­(1H-pyrazole-κN (2))copper(II)]-μ-hexa­fluoridosilicato-κ(2) F:F′]
title_full_unstemmed catena-Poly[[tetra­kis­(1H-pyrazole-κN (2))copper(II)]-μ-hexa­fluoridosilicato-κ(2) F:F′]
title_short catena-Poly[[tetra­kis­(1H-pyrazole-κN (2))copper(II)]-μ-hexa­fluoridosilicato-κ(2) F:F′]
title_sort catena-poly[[tetra­kis­(1h-pyrazole-κn (2))copper(ii)]-μ-hexa­fluoridosilicato-κ(2) f:f′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343814/
https://www.ncbi.nlm.nih.gov/pubmed/22589788
http://dx.doi.org/10.1107/S1600536812009531
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