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catena-Poly[[tetrakis(1H-pyrazole-κN (2))copper(II)]-μ-hexafluoridosilicato-κ(2) F:F′]
In the title one-dimensional coordination polymer, [Cu(SiF(6))(C(3)H(4)N(2))(4)](n), the Cu(II) atom is coordinated by two hexafluoridosilicate F atoms and four pyrazole N atoms in a distorted trans-CuF(2)N(4) octahedral environment. The dihedral angle between the planes of the pyrazlole rings in t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343814/ https://www.ncbi.nlm.nih.gov/pubmed/22589788 http://dx.doi.org/10.1107/S1600536812009531 |
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author | Li, Hui Han, Qiuping Chai, Xiaochuan Wang, Jian Yao, Chenzhong |
author_facet | Li, Hui Han, Qiuping Chai, Xiaochuan Wang, Jian Yao, Chenzhong |
author_sort | Li, Hui |
collection | PubMed |
description | In the title one-dimensional coordination polymer, [Cu(SiF(6))(C(3)H(4)N(2))(4)](n), the Cu(II) atom is coordinated by two hexafluoridosilicate F atoms and four pyrazole N atoms in a distorted trans-CuF(2)N(4) octahedral environment. The dihedral angle between the planes of the pyrazlole rings in the asymmetric unit is 74.4 (3)°. The hexafluoridosilicate dianion acts as a bridging ligand, connecting the Cu(II) atoms into a [1-10] chain. The Cu and Si atoms lie on special positions with 2/m site symmetry. In the crystal, intrachain N—H⋯F hydrogen bonds occur and weak C—H⋯F interactions link the chains. |
format | Online Article Text |
id | pubmed-3343814 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438142012-05-15 catena-Poly[[tetrakis(1H-pyrazole-κN (2))copper(II)]-μ-hexafluoridosilicato-κ(2) F:F′] Li, Hui Han, Qiuping Chai, Xiaochuan Wang, Jian Yao, Chenzhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [Cu(SiF(6))(C(3)H(4)N(2))(4)](n), the Cu(II) atom is coordinated by two hexafluoridosilicate F atoms and four pyrazole N atoms in a distorted trans-CuF(2)N(4) octahedral environment. The dihedral angle between the planes of the pyrazlole rings in the asymmetric unit is 74.4 (3)°. The hexafluoridosilicate dianion acts as a bridging ligand, connecting the Cu(II) atoms into a [1-10] chain. The Cu and Si atoms lie on special positions with 2/m site symmetry. In the crystal, intrachain N—H⋯F hydrogen bonds occur and weak C—H⋯F interactions link the chains. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343814/ /pubmed/22589788 http://dx.doi.org/10.1107/S1600536812009531 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Hui Han, Qiuping Chai, Xiaochuan Wang, Jian Yao, Chenzhong catena-Poly[[tetrakis(1H-pyrazole-κN (2))copper(II)]-μ-hexafluoridosilicato-κ(2) F:F′] |
title |
catena-Poly[[tetrakis(1H-pyrazole-κN
(2))copper(II)]-μ-hexafluoridosilicato-κ(2)
F:F′] |
title_full |
catena-Poly[[tetrakis(1H-pyrazole-κN
(2))copper(II)]-μ-hexafluoridosilicato-κ(2)
F:F′] |
title_fullStr |
catena-Poly[[tetrakis(1H-pyrazole-κN
(2))copper(II)]-μ-hexafluoridosilicato-κ(2)
F:F′] |
title_full_unstemmed |
catena-Poly[[tetrakis(1H-pyrazole-κN
(2))copper(II)]-μ-hexafluoridosilicato-κ(2)
F:F′] |
title_short |
catena-Poly[[tetrakis(1H-pyrazole-κN
(2))copper(II)]-μ-hexafluoridosilicato-κ(2)
F:F′] |
title_sort | catena-poly[[tetrakis(1h-pyrazole-κn
(2))copper(ii)]-μ-hexafluoridosilicato-κ(2)
f:f′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343814/ https://www.ncbi.nlm.nih.gov/pubmed/22589788 http://dx.doi.org/10.1107/S1600536812009531 |
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