3,5-Dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) S,S′)nickelate(III)

The asymmetric unit of the title compound, (C(14)H(15)N(2)O(2))[Ni(C(6)H(4)S(2))(2)], contains one cation and two halves of two centrosymmetric crystallographically independent anions. In the anions, the Ni(III) atoms are coordinated by four S atoms in a distorted square-planar geometry. In the cati...

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Autor principal: Liu, Guang-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343816/
https://www.ncbi.nlm.nih.gov/pubmed/22589790
http://dx.doi.org/10.1107/S1600536812009828
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author Liu, Guang-Xiang
author_facet Liu, Guang-Xiang
author_sort Liu, Guang-Xiang
collection PubMed
description The asymmetric unit of the title compound, (C(14)H(15)N(2)O(2))[Ni(C(6)H(4)S(2))(2)], contains one cation and two halves of two centrosymmetric crystallographically independent anions. In the anions, the Ni(III) atoms are coordinated by four S atoms in a distorted square-planar geometry. In the cation, the dihedral angle between the pyridine and benzene rings is 88.66 (17)°. In the crystal, anions and cations inter­act through C—H⋯S and C—H⋯O hydrogen bonds.
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spelling pubmed-33438162012-05-15 3,5-Dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) S,S′)nickelate(III) Liu, Guang-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(14)H(15)N(2)O(2))[Ni(C(6)H(4)S(2))(2)], contains one cation and two halves of two centrosymmetric crystallographically independent anions. In the anions, the Ni(III) atoms are coordinated by four S atoms in a distorted square-planar geometry. In the cation, the dihedral angle between the pyridine and benzene rings is 88.66 (17)°. In the crystal, anions and cations inter­act through C—H⋯S and C—H⋯O hydrogen bonds. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343816/ /pubmed/22589790 http://dx.doi.org/10.1107/S1600536812009828 Text en © Guang-Xiang Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Guang-Xiang
3,5-Dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) S,S′)nickelate(III)
title 3,5-Dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) S,S′)nickelate(III)
title_full 3,5-Dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) S,S′)nickelate(III)
title_fullStr 3,5-Dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) S,S′)nickelate(III)
title_full_unstemmed 3,5-Dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) S,S′)nickelate(III)
title_short 3,5-Dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) S,S′)nickelate(III)
title_sort 3,5-dimethyl-1-(4-nitro­benz­yl)pyridinium bis­(benzene-1,2-dithiol­ato-κ(2) s,s′)nickelate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343816/
https://www.ncbi.nlm.nih.gov/pubmed/22589790
http://dx.doi.org/10.1107/S1600536812009828
work_keys_str_mv AT liuguangxiang 35dimethyl14nitrobenzylpyridiniumbisbenzene12dithiolatok2ssnickelateiii

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