trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)

The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecules, one Cl(−) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecul...

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Detalles Bibliográficos
Autor principal: Wang, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343817/
https://www.ncbi.nlm.nih.gov/pubmed/22589791
http://dx.doi.org/10.1107/S1600536812010124
Descripción
Sumario:The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecules, one Cl(−) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecule. The distorted octa­hedral Mn environment comprises two terminal Cl atoms and four monodentate N atoms from four organic ligands. All the carbamoyl N atoms are involved in inter­molecular N—H⋯O hydrogen-bonding inter­actions which link the mol­ecules into a chain along the a axis.

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