trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)

The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecules, one Cl(−) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecul...

Descripción completa

Detalles Bibliográficos
Autor principal: Wang, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343817/
https://www.ncbi.nlm.nih.gov/pubmed/22589791
http://dx.doi.org/10.1107/S1600536812010124
_version_ 1782231851335680000
author Wang, Ying-Chun
author_facet Wang, Ying-Chun
author_sort Wang, Ying-Chun
collection PubMed
description The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecules, one Cl(−) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecule. The distorted octa­hedral Mn environment comprises two terminal Cl atoms and four monodentate N atoms from four organic ligands. All the carbamoyl N atoms are involved in inter­molecular N—H⋯O hydrogen-bonding inter­actions which link the mol­ecules into a chain along the a axis.
format Online
Article
Text
id pubmed-3343817
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33438172012-05-15 trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2) Wang, Ying-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecules, one Cl(−) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol­ecule. The distorted octa­hedral Mn environment comprises two terminal Cl atoms and four monodentate N atoms from four organic ligands. All the carbamoyl N atoms are involved in inter­molecular N—H⋯O hydrogen-bonding inter­actions which link the mol­ecules into a chain along the a axis. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343817/ /pubmed/22589791 http://dx.doi.org/10.1107/S1600536812010124 Text en © Ying-Chun Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ying-Chun
trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)
title trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)
title_full trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)
title_fullStr trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)
title_full_unstemmed trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)
title_short trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)
title_sort trans-tetra­kis[n-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(ii)–n-(adamantan-1-yl)pyridine-4-carboxamide (1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343817/
https://www.ncbi.nlm.nih.gov/pubmed/22589791
http://dx.doi.org/10.1107/S1600536812010124
work_keys_str_mv AT wangyingchun transtetrakisnadamantan1ylpyridine4carboxamidedichloridomanganeseiinadamantan1ylpyridine4carboxamide12

Ejemplares similares