(2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))cobalt(III)

The Co(III) atom in the title compound, [Co(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is six-coordinated in a distorted octa­hedral geometry by four N atoms and two O atoms of the chelating 2,2′-bipyridine-6,6′-dicarboxyl­ate and 6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ate ligands. Intermolecular O—H⋯O...

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Detalles Bibliográficos
Autores principales: Wang, Huimin, Gu, Xiaojun, Zhang, Bingbing, Su, Haiquan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343819/
https://www.ncbi.nlm.nih.gov/pubmed/22589793
http://dx.doi.org/10.1107/S1600536812009816
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author Wang, Huimin
Gu, Xiaojun
Zhang, Bingbing
Su, Haiquan
author_facet Wang, Huimin
Gu, Xiaojun
Zhang, Bingbing
Su, Haiquan
author_sort Wang, Huimin
collection PubMed
description The Co(III) atom in the title compound, [Co(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is six-coordinated in a distorted octa­hedral geometry by four N atoms and two O atoms of the chelating 2,2′-bipyridine-6,6′-dicarboxyl­ate and 6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ate ligands. Intermolecular O—H⋯O hydrogen bonds and face-to-face π-stacking inter­actions [centroid–centroid distance = 3.6352 (16) Å] between inversion-related pyridine rings link adjacent mononuclear units into a two-dimensional supra­molecular structure, and several inter­molecular C—H⋯O inter­actions are also observed.
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spelling pubmed-33438192012-05-15 (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))cobalt(III) Wang, Huimin Gu, Xiaojun Zhang, Bingbing Su, Haiquan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(III) atom in the title compound, [Co(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is six-coordinated in a distorted octa­hedral geometry by four N atoms and two O atoms of the chelating 2,2′-bipyridine-6,6′-dicarboxyl­ate and 6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ate ligands. Intermolecular O—H⋯O hydrogen bonds and face-to-face π-stacking inter­actions [centroid–centroid distance = 3.6352 (16) Å] between inversion-related pyridine rings link adjacent mononuclear units into a two-dimensional supra­molecular structure, and several inter­molecular C—H⋯O inter­actions are also observed. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343819/ /pubmed/22589793 http://dx.doi.org/10.1107/S1600536812009816 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Huimin
Gu, Xiaojun
Zhang, Bingbing
Su, Haiquan
(2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))cobalt(III)
title (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))cobalt(III)
title_full (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))cobalt(III)
title_fullStr (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))cobalt(III)
title_full_unstemmed (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))cobalt(III)
title_short (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))cobalt(III)
title_sort (2,2′-bipyridine-6,6′-dicarboxyl­ato-κ(3) n,n′,o (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) n,n′,o (6))cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343819/
https://www.ncbi.nlm.nih.gov/pubmed/22589793
http://dx.doi.org/10.1107/S1600536812009816
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