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cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN (3))phenyl]tetrazolido}manganese(II) dihydrate
In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the complex unit comprises an Mn(2+) ion, coordinated by two imidazole N atoms from cis-related monodentate 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four water molecules, together with two water molecules of solvation. The...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343820/ https://www.ncbi.nlm.nih.gov/pubmed/22589794 http://dx.doi.org/10.1107/S1600536812010380 |
| _version_ | 1782231852028788736 |
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| author | Wang, Xin Yan, Shi-Wei Chang, Suo-Cheng Liang, Yan-Chen Zhang, Fu-Tian |
| author_facet | Wang, Xin Yan, Shi-Wei Chang, Suo-Cheng Liang, Yan-Chen Zhang, Fu-Tian |
| author_sort | Wang, Xin |
| collection | PubMed |
| description | In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the complex unit comprises an Mn(2+) ion, coordinated by two imidazole N atoms from cis-related monodentate 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four water molecules, together with two water molecules of solvation. The Mn(2+) ion lies on a twofold rotation axis and has a slightly distorted octahedral geometry. The molecules are connected by O—H⋯N and O—H⋯O hydrogen bonds involving both coordinated and solvent water molecules, generating a three-dimensional structure. Two C atoms of the imidazole ring of the ligand are each disordered over two sites with occupancy factors of 0.75 and 0.25. |
| format | Online Article Text |
| id | pubmed-3343820 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438202012-05-15 cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN (3))phenyl]tetrazolido}manganese(II) dihydrate Wang, Xin Yan, Shi-Wei Chang, Suo-Cheng Liang, Yan-Chen Zhang, Fu-Tian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the complex unit comprises an Mn(2+) ion, coordinated by two imidazole N atoms from cis-related monodentate 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four water molecules, together with two water molecules of solvation. The Mn(2+) ion lies on a twofold rotation axis and has a slightly distorted octahedral geometry. The molecules are connected by O—H⋯N and O—H⋯O hydrogen bonds involving both coordinated and solvent water molecules, generating a three-dimensional structure. Two C atoms of the imidazole ring of the ligand are each disordered over two sites with occupancy factors of 0.75 and 0.25. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343820/ /pubmed/22589794 http://dx.doi.org/10.1107/S1600536812010380 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Xin Yan, Shi-Wei Chang, Suo-Cheng Liang, Yan-Chen Zhang, Fu-Tian cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN (3))phenyl]tetrazolido}manganese(II) dihydrate |
| title |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_full |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_fullStr |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_full_unstemmed |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_short |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_sort | cis-tetraaquabis{5-[4-(1h-imidazol-1-yl-κn
(3))phenyl]tetrazolido}manganese(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343820/ https://www.ncbi.nlm.nih.gov/pubmed/22589794 http://dx.doi.org/10.1107/S1600536812010380 |
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