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Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(N,N-dimethyl­acetamide)­terbium(III)]

The title compound, [Tb(C(9)H(3)O(6))(C(4)H(9)NO)(2)], shows a rare-earth three-dimensional metal-organic framework structure. In this complex of an eight-coordinated Tb(3+) ion, the asymmetric unit contains one benzene-1,3,5-tricarb­oxy­lic ligand and two coordinated dimethyl­acetamide mol­ecules....

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Detalles Bibliográficos
Autor principal: Liu, Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343821/
https://www.ncbi.nlm.nih.gov/pubmed/22589795
http://dx.doi.org/10.1107/S1600536812010264
Descripción
Sumario:The title compound, [Tb(C(9)H(3)O(6))(C(4)H(9)NO)(2)], shows a rare-earth three-dimensional metal-organic framework structure. In this complex of an eight-coordinated Tb(3+) ion, the asymmetric unit contains one benzene-1,3,5-tricarb­oxy­lic ligand and two coordinated dimethyl­acetamide mol­ecules. Each Tb(3+) ion is coordinated by six O atoms from four carboxyl­ate groups of the benzene-1,3,5-tricarb­oxy­lic ligands and two O atoms from two terminal dimethyl­acetamide mol­ecules.