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Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(N,N-dimethylacetamide)terbium(III)]
The title compound, [Tb(C(9)H(3)O(6))(C(4)H(9)NO)(2)], shows a rare-earth three-dimensional metal-organic framework structure. In this complex of an eight-coordinated Tb(3+) ion, the asymmetric unit contains one benzene-1,3,5-tricarboxylic ligand and two coordinated dimethylacetamide molecules....
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343821/ https://www.ncbi.nlm.nih.gov/pubmed/22589795 http://dx.doi.org/10.1107/S1600536812010264 |
Sumario: | The title compound, [Tb(C(9)H(3)O(6))(C(4)H(9)NO)(2)], shows a rare-earth three-dimensional metal-organic framework structure. In this complex of an eight-coordinated Tb(3+) ion, the asymmetric unit contains one benzene-1,3,5-tricarboxylic ligand and two coordinated dimethylacetamide molecules. Each Tb(3+) ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylic ligands and two O atoms from two terminal dimethylacetamide molecules. |
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