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Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]

The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octa­hedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms fr...

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Detalles Bibliográficos
Autores principales: Wu, Longfei, Huang, Linxia, Shu, Mouhai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343826/
https://www.ncbi.nlm.nih.gov/pubmed/22589800
http://dx.doi.org/10.1107/S1600536812010355
Descripción
Sumario:The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octa­hedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms from a water mol­ecule, two nitrates and two hydroxides. Two Cu(II) ions are bridged by two hydroxide anions resulting in a Cu(2)O(2) loop, located across an inversion center and connected by the nitrate anions into a broad two-dimensional polymeric structure parallel to (100). In the crystal, there are O—H⋯O hydrogen bonds between the coodinated water mol­ecule and the nitrate and hydroxide, and between the hydroxide and the nitrate. Inter­molecular π–π inter­actions are present between pyridine rings in adjacent two-dimensional structures, with a centroid–centroid distance of 3.582 (2) Å.